том 54 издание 23 страницы 2850-2853

Diels-Alder reactions between hexafluoro-2-butyne and bis-furyl dienes: kinetic versus thermodynamic control.

Тип публикацииJournal Article
Дата публикации2018-02-02
scimago Q1
wos Q2
БС1
SJR1.037
CiteScore7.4
Impact factor4.2
ISSN13597345, 1364548X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Краткое описание
The tandem [4+2] cycloaddition between hexafluoro-2-butyne and bis-furyl dienes, like difurfuryl ester, at room temperature leads to the kinetically controlled "pincer"-adducts - annulated 4a,8a-bis(trifluoromethyl)hexahydro-1,4:5,8-diepoxynaphthalenes. On the other hand, if these reactions proceed at 140 °C, only the thermodynamically controlled "domino"-adducts - annulated 2,3-bis(trifluoromethyl)hexahydro-1,4:5,8-diepoxynaphthalenes - are formed. Therefore, a very rare and unexpected example of full kinetic and thermodynamic control in the Diels-Alder reaction is reported in this paper.
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ГОСТ |
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Borisova K. K. et al. Diels-Alder reactions between hexafluoro-2-butyne and bis-furyl dienes: kinetic versus thermodynamic control. // Chemical Communications. 2018. Vol. 54. No. 23. pp. 2850-2853.
ГОСТ со всеми авторами (до 50) Скопировать
Borisova K. K. et al. Diels-Alder reactions between hexafluoro-2-butyne and bis-furyl dienes: kinetic versus thermodynamic control. // Chemical Communications. 2018. Vol. 54. No. 23. pp. 2850-2853.
RIS |
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TY - JOUR
DO - 10.1039/C7CC09466C
UR - https://xlink.rsc.org/?DOI=C7CC09466C
TI - Diels-Alder reactions between hexafluoro-2-butyne and bis-furyl dienes: kinetic versus thermodynamic control.
T2 - Chemical Communications
AU - Borisova, Kseniya K
AU - Nikitina, Eugeniya V.
AU - Novikov, Roman G.
AU - Khrustalev, Victor N.
AU - Dorovatovskii, Pavel
AU - Zubavichus, Yan V.
AU - Kuznetsov, Maxim
AU - Zaytsev, Vladimir P.
AU - Varlamov, Alexey V.
AU - Zubkov, Fedor I.
PY - 2018
DA - 2018/02/02
PB - Royal Society of Chemistry (RSC)
SP - 2850-2853
IS - 23
VL - 54
PMID - 29393318
SN - 1359-7345
SN - 1364-548X
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2018_Borisova,
author = {Kseniya K Borisova and Eugeniya V. Nikitina and Roman G. Novikov and Victor N. Khrustalev and Pavel Dorovatovskii and Yan V. Zubavichus and Maxim Kuznetsov and Vladimir P. Zaytsev and Alexey V. Varlamov and Fedor I. Zubkov and others},
title = {Diels-Alder reactions between hexafluoro-2-butyne and bis-furyl dienes: kinetic versus thermodynamic control.},
journal = {Chemical Communications},
year = {2018},
volume = {54},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://xlink.rsc.org/?DOI=C7CC09466C},
number = {23},
pages = {2850--2853},
doi = {10.1039/C7CC09466C}
}
MLA
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Borisova, Kseniya K., et al. “Diels-Alder reactions between hexafluoro-2-butyne and bis-furyl dienes: kinetic versus thermodynamic control..” Chemical Communications, vol. 54, no. 23, Feb. 2018, pp. 2850-2853. https://xlink.rsc.org/?DOI=C7CC09466C.