Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties
Viktoria V Khistiaeva
1, 2, 3, 4, 5
,
A Melnikov
5, 6, 7, 8, 9
,
Sofia Slavova
1, 2, 3, 4, 5
,
V. Sizov
1, 2, 3, 4, 5
,
G. L. Starova
1, 2, 3, 4, 5
,
Igor O Koshevoy
10, 11, 12, 13, 14
,
Elena V Grachova
1, 2, 3, 4, 5
2
Institute of Chemistry
4
198504 St. Petersburg
5
Russia
|
7
Centre for Nano- and Biotechnologies
9
195251 St. Petersburg
11
DEPARTMENT OF CHEMISTRY
13
80101 Joensuu
|
14
FINLAND
|
Publication type: Journal Article
Publication date: 2018-09-19
scimago Q1
wos Q1
SJR: 1.276
CiteScore: 9.9
Impact factor: 6.4
ISSN: 20521545, 20521553
Inorganic Chemistry
Abstract
A substituted pyridazine was used to construct a family of mononuclear heteroleptic complexes [Ln(tta)3(dppn)], Ln = Pr–Lu; Htta = thenoyltrifluoroacetone; dppn = 3,6-di(2-pyridyl)pyridazine. All the complexes obtained were characterized by CHN elemental analysis, NMR spectroscopy, ESI mass spectrometry, FTIR spectroscopy and single crystal X-ray analysis. The photophysical properties of lanthanide complexes were carefully investigated, and the dppn ligand was found to act as a chromophore centre to sensitize metal-centred emission of the Nd, Sm, Eu, and Yb complexes under UV excitation. It has been shown that a powder sample of the Eu complex can contain two isomers with somewhat different symmetries of the environment of the metallocentre. The mechanism for the emission of luminescent Nd, Sm, Eu, and Yb complexes was investigated by TDDFT calculations and the results confirmed the conclusion made on the basis of experimental data regarding the likely pathway of energy transfer from the chromophore centre to the emissive level of Ln(III).
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Total citations:
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Citations from 2024:
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(17%)
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Khistiaeva V. V. et al. Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties // Inorganic Chemistry Frontiers. 2018. Vol. 5. No. 12. pp. 3015-3027.
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Khistiaeva V. V., Melnikov A., Slavova S., Sizov V., Starova G. L., Koshevoy I. O., Grachova E. V. Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties // Inorganic Chemistry Frontiers. 2018. Vol. 5. No. 12. pp. 3015-3027.
Cite this
RIS
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TY - JOUR
DO - 10.1039/C8QI00712H
UR - https://xlink.rsc.org/?DOI=C8QI00712H
TI - Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties
T2 - Inorganic Chemistry Frontiers
AU - Khistiaeva, Viktoria V
AU - Melnikov, A
AU - Slavova, Sofia
AU - Sizov, V.
AU - Starova, G. L.
AU - Koshevoy, Igor O
AU - Grachova, Elena V
PY - 2018
DA - 2018/09/19
PB - Royal Society of Chemistry (RSC)
SP - 3015-3027
IS - 12
VL - 5
SN - 2052-1545
SN - 2052-1553
ER -
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BibTex (up to 50 authors)
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@article{2018_Khistiaeva,
author = {Viktoria V Khistiaeva and A Melnikov and Sofia Slavova and V. Sizov and G. L. Starova and Igor O Koshevoy and Elena V Grachova},
title = {Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties},
journal = {Inorganic Chemistry Frontiers},
year = {2018},
volume = {5},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://xlink.rsc.org/?DOI=C8QI00712H},
number = {12},
pages = {3015--3027},
doi = {10.1039/C8QI00712H}
}
Cite this
MLA
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Khistiaeva, Viktoria V., et al. “Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties.” Inorganic Chemistry Frontiers, vol. 5, no. 12, Sep. 2018, pp. 3015-3027. https://xlink.rsc.org/?DOI=C8QI00712H.
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