Inorganic Chemistry Frontiers, volume 5, issue 12, pages 3015-3027
Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties
Khistiaeva Viktoria V
1
,
Melnikov A
2
,
Slavova Sofia
1
,
Sizov V.
1
,
Starova G. L.
1
,
Koshevoy Igor O
3
,
Publication type: Journal Article
Publication date: 2018-09-19
Journal:
Inorganic Chemistry Frontiers
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 7
ISSN: 20521545, 20521553
Inorganic Chemistry
Abstract
A substituted pyridazine was used to construct a family of mononuclear heteroleptic complexes [Ln(tta)3(dppn)], Ln = Pr–Lu; Htta = thenoyltrifluoroacetone; dppn = 3,6-di(2-pyridyl)pyridazine. All the complexes obtained were characterized by CHN elemental analysis, NMR spectroscopy, ESI mass spectrometry, FTIR spectroscopy and single crystal X-ray analysis. The photophysical properties of lanthanide complexes were carefully investigated, and the dppn ligand was found to act as a chromophore centre to sensitize metal-centred emission of the Nd, Sm, Eu, and Yb complexes under UV excitation. It has been shown that a powder sample of the Eu complex can contain two isomers with somewhat different symmetries of the environment of the metallocentre. The mechanism for the emission of luminescent Nd, Sm, Eu, and Yb complexes was investigated by TDDFT calculations and the results confirmed the conclusion made on the basis of experimental data regarding the likely pathway of energy transfer from the chromophore centre to the emissive level of Ln(III).
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Khistiaeva V. V. et al. Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties // Inorganic Chemistry Frontiers. 2018. Vol. 5. No. 12. pp. 3015-3027.
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Khistiaeva V. V., Melnikov A., Slavova S., Sizov V., Starova G. L., Koshevoy I. O., Grachova E. V. Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties // Inorganic Chemistry Frontiers. 2018. Vol. 5. No. 12. pp. 3015-3027.
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TY - JOUR
DO - 10.1039/C8QI00712H
UR - https://doi.org/10.1039%2FC8QI00712H
TI - Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties
T2 - Inorganic Chemistry Frontiers
AU - Khistiaeva, Viktoria V
AU - Melnikov, A
AU - Slavova, Sofia
AU - Sizov, V.
AU - Starova, G. L.
AU - Koshevoy, Igor O
AU - Grachova, Elena V
PY - 2018
DA - 2018/09/19 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 3015-3027
IS - 12
VL - 5
SN - 2052-1545
SN - 2052-1553
ER -
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@article{2018_Khistiaeva,
author = {Viktoria V Khistiaeva and A Melnikov and Sofia Slavova and V. Sizov and G. L. Starova and Igor O Koshevoy and Elena V Grachova},
title = {Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties},
journal = {Inorganic Chemistry Frontiers},
year = {2018},
volume = {5},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://doi.org/10.1039%2FC8QI00712H},
number = {12},
pages = {3015--3027},
doi = {10.1039/C8QI00712H}
}
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Khistiaeva, Viktoria V., et al. “Heteroleptic β-diketonate Ln(III) complexes decorated with pyridyl substituted pyridazine ligands: synthesis, structure and luminescence properties.” Inorganic Chemistry Frontiers, vol. 5, no. 12, Sep. 2018, pp. 3015-3027. https://doi.org/10.1039%2FC8QI00712H.
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