Chemical Communications, issue 21, pages 2151-2153
Total synthesis of (−)-conocarpan and assignment of the absolute configuration by chemical methods
Derrick L.J Clive
1
,
Elia J.L. Stoffman
1
Publication type: Journal Article
Publication date: 2007-05-10
Journal:
Chemical Communications
scimago Q1
SJR: 1.133
CiteScore: 8.6
Impact factor: 4.3
ISSN: 13597345, 1364548X
DOI:
10.1039/b704211f
PubMed ID:
17520119
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
(-)-Conocarpan (1) was synthesized by a method based on radical cyclization, and the absolute configuration was established by chemical degradation; the original 2R,3R-assignment to (+)-conocarpan should be reversed, as suggested by a later chiroptical study of model 2,3-dihydrobenzofurans.
Found
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