Au(i)-benzimidazole/imidazole complexes. Liquid crystals and nanomaterials
Publication type: Journal Article
Publication date: 2008-02-27
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
DOI:
10.1039/b717787a
PubMed ID:
18369500
Inorganic Chemistry
Abstract
Three series of Au(I)-imidazole complexes with stoichiometries of [Au(Cn-bim)Cl], [Au(Cn-im)Cl], and [Au(Cn-im)2][NO3] x 2H2O (Cn-bim = N-CnH2n+1 -substituted benzimidazole and Cn-im = N-CnH2n+1-substituted imidazole) together with the compound of [Au(C18-bim)2][NO3] are synthesiszed. Typical structures of each series are determined by single crystal X-ray diffraction. The last series of compounds, are liquid crystals, and exhibit a wider mesophase range than their Ag(I) analogues. These Au(I) complexes form Au nanostructures both through chemical reduction or thermolysis. For the first time, N-long chain imidazole is utilized to stabilize colloidal Au in solution. Also for the first time, unique examples of simple thermolysis to produce large Au plates of nanothickness are demonstrated. Formation of a plate-like morphology through fusion of sphere-like nanoparticles at an early stage is evidenced by TEM images.
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Metrics
40
Total citations:
40
Citations from 2024:
3
(7.5%)
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GOST
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Hsu S. J. et al. Au(i)-benzimidazole/imidazole complexes. Liquid crystals and nanomaterials // Dalton Transactions. 2008. Vol. 14. p. 1924.
GOST all authors (up to 50)
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Hsu S. J., Hsu K. M., Leong M. K., Lin I. B. Au(i)-benzimidazole/imidazole complexes. Liquid crystals and nanomaterials // Dalton Transactions. 2008. Vol. 14. p. 1924.
Cite this
RIS
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TY - JOUR
DO - 10.1039/b717787a
UR - https://doi.org/10.1039/b717787a
TI - Au(i)-benzimidazole/imidazole complexes. Liquid crystals and nanomaterials
T2 - Dalton Transactions
AU - Hsu, S J
AU - Hsu, K. M.
AU - Leong, Max K.
AU - Lin, Ivan B.
PY - 2008
DA - 2008/02/27
PB - Royal Society of Chemistry (RSC)
SP - 1924
IS - 14
PMID - 18369500
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2008_Hsu,
author = {S J Hsu and K. M. Hsu and Max K. Leong and Ivan B. Lin},
title = {Au(i)-benzimidazole/imidazole complexes. Liquid crystals and nanomaterials},
journal = {Dalton Transactions},
year = {2008},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039/b717787a},
number = {14},
pages = {1924},
doi = {10.1039/b717787a}
}