Observation of heavy atom effects in the development of water soluble caged 4-hydroxy-trans-2-nonenal
Тип публикации: Journal Article
Дата публикации: 2008-09-19
scimago Q2
wos Q2
БС1
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
18972051
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
During the course of our study on the photochemistry of 1-alkoxy-9,10-anthraquinones, we have developed a second generation of a caged 4-hydroxy-trans-2-nonenal (4-HNE). As we optimized the anthraquinonyl chromophore to achieve water solubility, we studied the photochemistry of various substituents to understand their effect on the photochemistry. We observed a significant heavy atom effect that severely reduced the rate of oxidative cleavage of the alkoxy group. Based on the results of our substituent study, we designed a new caged 4-HNE that is soluble under physiological conditions, and that releases 4-HNE photochemically in high yield.
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Paul H. Jones P. et al. Observation of heavy atom effects in the development of water soluble caged 4-hydroxy-trans-2-nonenal // Organic and Biomolecular Chemistry. 2008. Vol. 6. No. 22. p. 4204.
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Paul H. Jones P., BRINSON R. R., Sarma S. C., Elkazaz S. Observation of heavy atom effects in the development of water soluble caged 4-hydroxy-trans-2-nonenal // Organic and Biomolecular Chemistry. 2008. Vol. 6. No. 22. p. 4204.
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TY - JOUR
DO - 10.1039/b810954k
UR - https://doi.org/10.1039/b810954k
TI - Observation of heavy atom effects in the development of water soluble caged 4-hydroxy-trans-2-nonenal
T2 - Organic and Biomolecular Chemistry
AU - Paul H. Jones, Paul
AU - BRINSON, ROBERT R.
AU - Sarma, Saurav Chandra
AU - Elkazaz, Salwa
PY - 2008
DA - 2008/09/19
PB - Royal Society of Chemistry (RSC)
SP - 4204
IS - 22
VL - 6
PMID - 18972051
SN - 1477-0520
SN - 1477-0539
ER -
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@article{2008_Paul H. Jones,
author = {Paul Paul H. Jones and ROBERT R. BRINSON and Saurav Chandra Sarma and Salwa Elkazaz},
title = {Observation of heavy atom effects in the development of water soluble caged 4-hydroxy-trans-2-nonenal},
journal = {Organic and Biomolecular Chemistry},
year = {2008},
volume = {6},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://doi.org/10.1039/b810954k},
number = {22},
pages = {4204},
doi = {10.1039/b810954k}
}
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MLA
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Paul H. Jones, Paul, et al. “Observation of heavy atom effects in the development of water soluble caged 4-hydroxy-trans-2-nonenal.” Organic and Biomolecular Chemistry, vol. 6, no. 22, Sep. 2008, p. 4204. https://doi.org/10.1039/b810954k.