Chemical Communications, volume 47, issue 8, pages 2261
Pyridine as trigger for chloride isomerisation in chelated ruthenium benzylidene complexes: implications for olefin metathesis
Michaela Zirngast
1
,
Eva Pump
1
,
Anita Leitgeb
1
,
Jörg H. Albering
1
,
Christian Slugovc
1
Publication type: Journal Article
Publication date: 2011-01-21
Journal:
Chemical Communications
scimago Q1
SJR: 1.133
CiteScore: 8.6
Impact factor: 4.3
ISSN: 13597345, 1364548X
PubMed ID:
21253629
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The cationic pyridine adduct of a ruthenium complex bearing a chelating benzylidene and an N-heterocyclic carbene was identified as an intermediate during the activation of cis dichloro species and a novel triggering concept for olefin metathesis catalysts based on cationic species was disclosed.
Found
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