Comparison of different ruthenium–alkylidene bonds in the activation step with N-heterocyclic carbene Ru-catalysts for olefins metathesis
Publication type: Journal Article
Publication date: 2011-08-09
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
21829796
Inorganic Chemistry
Abstract
Density functional theory calculations have been used to investigate the activation steps involving three of the most used alkylidene groups in Ru-catalysts for olefins metathesis. Specifically, we compared the benzylidene, the indenylidene and a phosphonium alkylidene groups. Calculations reveal that the benzylidene and the indenylidene groups behave rather similarly, despite their structural differences. The phosphonium alkylidene group seems to have the most favourable activation pathway.
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60
Total citations:
60
Citations from 2024:
5
(8.47%)
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MLA
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GOST
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Poater A. et al. Comparison of different ruthenium–alkylidene bonds in the activation step with N-heterocyclic carbene Ru-catalysts for olefins metathesis // Dalton Transactions. 2011. Vol. 40. No. 42. p. 11066.
GOST all authors (up to 50)
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Poater A., Ragone F., Correa A., Cavallo L. M. Comparison of different ruthenium–alkylidene bonds in the activation step with N-heterocyclic carbene Ru-catalysts for olefins metathesis // Dalton Transactions. 2011. Vol. 40. No. 42. p. 11066.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c1dt10959f
UR - https://doi.org/10.1039/c1dt10959f
TI - Comparison of different ruthenium–alkylidene bonds in the activation step with N-heterocyclic carbene Ru-catalysts for olefins metathesis
T2 - Dalton Transactions
AU - Poater, Albert
AU - Ragone, F
AU - Correa, Andrea
AU - Cavallo, Luigi Maria
PY - 2011
DA - 2011/08/09
PB - Royal Society of Chemistry (RSC)
SP - 11066
IS - 42
VL - 40
PMID - 21829796
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Poater,
author = {Albert Poater and F Ragone and Andrea Correa and Luigi Maria Cavallo},
title = {Comparison of different ruthenium–alkylidene bonds in the activation step with N-heterocyclic carbene Ru-catalysts for olefins metathesis},
journal = {Dalton Transactions},
year = {2011},
volume = {40},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://doi.org/10.1039/c1dt10959f},
number = {42},
pages = {11066},
doi = {10.1039/c1dt10959f}
}
Cite this
MLA
Copy
Poater, Albert, et al. “Comparison of different ruthenium–alkylidene bonds in the activation step with N-heterocyclic carbene Ru-catalysts for olefins metathesis.” Dalton Transactions, vol. 40, no. 42, Aug. 2011, p. 11066. https://doi.org/10.1039/c1dt10959f.
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