Chemical Communications, volume 48, issue 9, pages 1266-1268

An unusual cationic Ru(ii) indenylidene complex and its Ru(iii) derivative—efficient catalysts for high temperature olefinmetathesis reactions

Publication type: Journal Article
Publication date: 2012-01-01
scimago Q1
SJR: 1.133
CiteScore: 8.6
Impact factor: 4.3
ISSN: 13597345, 1364548X
DOI:  10.1039/c2cc15903a
PubMed ID:  22179224
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The use of a mixed phosphite/N-heterocyclic carbene bearing ruthenium precursor permits the synthesis and characterisation of unprecedented four-coordinate Ru(II) and Ru(III) cationic complexes adopting an unusual sawhorse structure. The cationic Ru(II) complex performs very effectively on challenging substrates at high temperature in very short reaction times and low catalyst loadings.
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