Journal of the Chemical Society Chemical Communications, issue 15, pages 636-637

New nickel–carbon dioxide complex: synthesis, properties, and crystallographic characterization of (carbon dioxide)-bis(tricyclohexylphosphine)nickel

Michele Aresta
C Francesco Nobile
Vincenzo G. Albano
Elisabetta Forni
Mario Manassero
Publication typeJournal Article
Publication date1975-01-01
Quartile SCImago
Quartile WOS
Impact factor
ISSN00224936
Molecular Medicine
Abstract
[Ni(CO2)(PCy3)2],0·75(C7H8), where Cy = cyclohexyl, can be made either by treating [Ni(PCy3)3] or [{Ni(PCy3)2}2N2] with CO2 in toluene, or by direct reduction of [NiBr2(PCy3)2] with sodium sand under CO2; the complex is planar, the CO2 ligand possesses bent geometry and is co-ordinated through the carbon atom and one of the oxygen atoms.

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Aresta M. et al. New nickel–carbon dioxide complex: synthesis, properties, and crystallographic characterization of (carbon dioxide)-bis(tricyclohexylphosphine)nickel // Journal of the Chemical Society Chemical Communications. 1975. Vol. 15. pp. 636-637.
GOST all authors (up to 50) Copy
Aresta M., Nobile C. F., Albano V. G., Forni E., Manassero M. New nickel–carbon dioxide complex: synthesis, properties, and crystallographic characterization of (carbon dioxide)-bis(tricyclohexylphosphine)nickel // Journal of the Chemical Society Chemical Communications. 1975. Vol. 15. pp. 636-637.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/c39750000636
UR - https://doi.org/10.1039/c39750000636
TI - New nickel–carbon dioxide complex: synthesis, properties, and crystallographic characterization of (carbon dioxide)-bis(tricyclohexylphosphine)nickel
T2 - Journal of the Chemical Society Chemical Communications
AU - Nobile, C Francesco
AU - Albano, Vincenzo G.
AU - Forni, Elisabetta
AU - Manassero, Mario
AU - Aresta, Michele
PY - 1975
DA - 1975/01/01
PB - Royal Society of Chemistry (RSC)
SP - 636-637
IS - 15
SN - 0022-4936
ER -
BibTex
Cite this
BibTex Copy
@article{1975_Aresta,
author = {C Francesco Nobile and Vincenzo G. Albano and Elisabetta Forni and Mario Manassero and Michele Aresta},
title = {New nickel–carbon dioxide complex: synthesis, properties, and crystallographic characterization of (carbon dioxide)-bis(tricyclohexylphosphine)nickel},
journal = {Journal of the Chemical Society Chemical Communications},
year = {1975},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c39750000636},
number = {15},
pages = {636--637},
doi = {10.1039/c39750000636}
}
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