The decarboxylative route to azomethine ylides. Mechanism of 1,3-dipole formation

Ronald Grigg
Jonathan Idle
Peter McMeekin
David Vipond
Publication typeJournal Article
Publication date1987-01-01
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ISSN00224936
Molecular Medicine
Abstract
Evidence is presented that indicates that the decarboxylative route to azomethine ylides from both primary and secondary, cyclic and acyclic, α-amino acids involves an intermediate oxazolidin-5-one which loses carbon dioxide in a 1,3-dipolar cycloreversion reaction to generate an azomethine ylide stereospecifically.
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GOST Copy
Grigg R. et al. The decarboxylative route to azomethine ylides. Mechanism of 1,3-dipole formation // Journal of the Chemical Society Chemical Communications. 1987. Vol. 2. p. 49.
GOST all authors (up to 50) Copy
Grigg R., Idle J., McMeekin P., Vipond D. The decarboxylative route to azomethine ylides. Mechanism of 1,3-dipole formation // Journal of the Chemical Society Chemical Communications. 1987. Vol. 2. p. 49.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/c39870000049
UR - https://doi.org/10.1039/c39870000049
TI - The decarboxylative route to azomethine ylides. Mechanism of 1,3-dipole formation
T2 - Journal of the Chemical Society Chemical Communications
AU - Grigg, Ronald
AU - Idle, Jonathan
AU - McMeekin, Peter
AU - Vipond, David
PY - 1987
DA - 1987/01/01
PB - Royal Society of Chemistry (RSC)
SP - 49
IS - 2
SN - 0022-4936
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{1987_Grigg,
author = {Ronald Grigg and Jonathan Idle and Peter McMeekin and David Vipond},
title = {The decarboxylative route to azomethine ylides. Mechanism of 1,3-dipole formation},
journal = {Journal of the Chemical Society Chemical Communications},
year = {1987},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c39870000049},
number = {2},
pages = {49},
doi = {10.1039/c39870000049}
}