Chemical Communications, volume 51, issue 54, pages 10907-10909
Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight
S Chantal E Stieber
1
,
Núria Huguet
1
,
Takeharu Kageyama
1
,
Ivana Jevtovikj
1
,
Piyal Ariyananda
1
,
Alvaro Gordillo
1, 2
,
Stephan A. Schunk
2
,
Frank Rominger
3
,
Peter Hofmann
1, 3
,
Michael Limbach
1, 4
1
CaRLa (Catalysis Research Laboratory), Im Neuenheimer Feld 584, 69120 Heidelberg, Germany
|
2
hte Aktiengesellschaft, Kurpfalzring 104, 69123 Heidelberg, Germany
|
4
BASF SE, Carl-Bosch-Strasse 38, 67056 Ludwigshafen, Germany
|
Publication type: Journal Article
Publication date: 2015-06-03
Journal:
Chemical Communications
scimago Q1
SJR: 1.133
CiteScore: 8.6
Impact factor: 4.3
ISSN: 13597345, 1364548X
PubMed ID:
26060842
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.
Found
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