Synthesis and unique reversible splitting of 14-membered cyclic aminomethylphosphines on to 7-membered heterocycles
Elvira Musina
1
,
Tatiana I Fesenko
1
,
Igor D Strelnik
1
,
Fedor M Polyancev
1
,
Shamil Latypov
1
,
Peter Lönnecke
2
,
Andrey A Karasik
1
,
Publication type: Journal Article
Publication date: 2015-06-16
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
26135988
Inorganic Chemistry
Abstract
A novel type of 14-membered cyclic polyphosphine, namely 1,8-diaza-3,6,10,13-tetraphosphacyclotetradecanes 2a–4ahas been synthesized by the condensation of 1,2-bis(phenylphosphino)ethane, formaldehyde and alkylamines (isopropylamine, ethylamine and cyclohexylamine) as a RRRR/SSSS-stereoisomer. The structure of macrocycle 2a was investigated by NMR-spectroscopy and X-ray crystal structure analysis. The unique reversible processes of macrocycles 2a–4a splitting onto the corresponding rac- (2b–4b) and meso- (2c–4c) stereoisomers of 1-aza-3,6-diphosphacycloheptanes were discovered.
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28
Total citations:
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Citations from 2024:
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(10.71%)
The most citing journal
Citations in journal:
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MLA
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GOST
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Musina E. et al. Synthesis and unique reversible splitting of 14-membered cyclic aminomethylphosphines on to 7-membered heterocycles // Dalton Transactions. 2015. Vol. 44. No. 30. pp. 13565-13572.
GOST all authors (up to 50)
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Musina E., Fesenko T. I., Strelnik I. D., Polyancev F. M., Latypov S., Lönnecke P., Hey-Hawkins E., Karasik A. A., Sinyashin O. G. Synthesis and unique reversible splitting of 14-membered cyclic aminomethylphosphines on to 7-membered heterocycles // Dalton Transactions. 2015. Vol. 44. No. 30. pp. 13565-13572.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c5dt01910a
UR - https://xlink.rsc.org/?DOI=C5DT01910A
TI - Synthesis and unique reversible splitting of 14-membered cyclic aminomethylphosphines on to 7-membered heterocycles
T2 - Dalton Transactions
AU - Musina, Elvira
AU - Fesenko, Tatiana I
AU - Strelnik, Igor D
AU - Polyancev, Fedor M
AU - Latypov, Shamil
AU - Lönnecke, Peter
AU - Hey-Hawkins, Evamarie
AU - Karasik, Andrey A
AU - Sinyashin, Oleg G.
PY - 2015
DA - 2015/06/16
PB - Royal Society of Chemistry (RSC)
SP - 13565-13572
IS - 30
VL - 44
PMID - 26135988
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Musina,
author = {Elvira Musina and Tatiana I Fesenko and Igor D Strelnik and Fedor M Polyancev and Shamil Latypov and Peter Lönnecke and Evamarie Hey-Hawkins and Andrey A Karasik and Oleg G. Sinyashin},
title = {Synthesis and unique reversible splitting of 14-membered cyclic aminomethylphosphines on to 7-membered heterocycles},
journal = {Dalton Transactions},
year = {2015},
volume = {44},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://xlink.rsc.org/?DOI=C5DT01910A},
number = {30},
pages = {13565--13572},
doi = {10.1039/c5dt01910a}
}
Cite this
MLA
Copy
Musina, Elvira, et al. “Synthesis and unique reversible splitting of 14-membered cyclic aminomethylphosphines on to 7-membered heterocycles.” Dalton Transactions, vol. 44, no. 30, Jun. 2015, pp. 13565-13572. https://xlink.rsc.org/?DOI=C5DT01910A.