Open Access
Open access
Royal Society of Chemistry (RSC)
Dalton Transactions
,  volume 46 ,  issue 45 ,  pages 15651-15655

Unexpected formation of a μ-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru3(CO)12 and its catalytic actIVity in carbene transfer reactions

Andrey P Kroitor 1, 2, 3, 4
, 
Lucie P. Cailler 5, 6, 7, 8, 9
, 
Alexander G. Martynov 3, 4, 10, 11
, 
Yulia G. Gorbunova 3, 4, 10, 11, 12
, 
Aslan Tsivadze 3, 4, 10, 11, 12
, 
Aslan Yu. Tsivadze 3, 4, 10, 11, 12
, 
Alexander B Sorokin 5, 6, 7, 8, 9
1
 
Chemical Department
2
 
3
 
Moscow
4
 
Russia | 
5
 
6
 
UMR 5256
7
 
8
 
69626 Villeurbanne Cedex | 
9
 
FRANCE | 
10
 
11
 
RUSSIAN ACADEMY OF SCIENCES
12
 
Publication type: Journal Article
Publication date: 2017-10-16
Royal Society of Chemistry (RSC)
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
DOI:  10.1039/c7dt03703a
PubMed ID:  29085924
Inorganic Chemistry
Abstract

Catalytic activity of novel μ-carbido Ru(iv) bisphthalocyaninate was firstly demonstrated by the olefin cyclopropanation and carbene insertion into N–H bonds.

Found 
Found 
13 citations
Martynov Alexander
🥼 🤝
DSc in Chemistry, associate member of the Russian Academy of Sciences 
122 publications,  2 042 citations,  63 reviews
h-index: 25
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Research interests
Chemistry
Coordination Chemistry
Inorganic Chemistry
Organic Chemistry
Phthalocyanines
Physical Chemistry
Rare Earth elements
Spectroscopy
Supramolecular chemistry
12 citations
Gorbunova Yuliya
DSc in Chemistry, professor, full member of the Russian Academy of Sciences 
284 publications,  4 398 citations,  65 reviews
h-index: 34
Lomonosov Moscow State University
Lomonosov Moscow State University
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Research interests
Coordination Chemistry
Lanthanides
Supramolecular chemistry
Tetrapyrrolic compounds
9 citations
Kroitor Andrey
🥼
PhD in Chemistry
13 publications,  106 citations
h-index: 6
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Research interests
Asymmetric metal complex catalysis
Catalysis
Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials
Coordination Chemistry
NMR spectroscopy
Organic Chemistry
Organic Electronics
Organic synthesis
Organoelement chemistry
Physical Chemistry
5 citations
Dmitrienko Alexander
🥼 🤝
7 publications,  24 citations
h-index: 3
Lomonosov Moscow State University
Lomonosov Moscow State University
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Research interests
Catalysis
Coordination chemistry
Density functional theory (DFT)
Inorganic Chemistry
Organic Chemistry
Quantum Chemistry
2 citations
Sorokin Pavel
🥼 🤝
DSc in Physics and Mathematics, associate professor
200 publications,  8 160 citations,  21 reviews
h-index: 40
National University of Science & Technology (MISiS)
National University of Science & Technology (MISiS)
Institute of Microelectronics Technology and High Purity Materials of the Russian Academy of Sciences
Institute of Microelectronics Technology and High Purity Materials of the Russian Academy of Sciences
Research interests
2D Materials
Ab initio
Computational chemistry
Condensed matter physics
Density functional theory (DFT)
Machine learning
Magnetic materials
Materials Science
Metals and alloys
Nanomaterials
Nanomaterials for biomedicine
Non-covalent Interactions
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Thin solid films
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G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
Ivanovo State University of Chemistry and Technology
Ivanovo State University of Chemistry and Technology
Research interests
Coordination Chemistry
Heterocyclic compounds
Macroheterocyclic compounds
Organic Chemistry
Synthesis of metal complexes
1 citation
Osipov Sergey
DSc in Chemistry
138 publications,  2 739 citations,  3 reviews
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A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
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North Caucasus Federal University
Kuban State University
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Biological activity
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Malononitrile
Selenoamides
Thioamides
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Zagidullin Almaz
🥼 🤝
PhD in Chemistry
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A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences
Research interests
Asymmetric metal complex catalysis
Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials
Coordination chemistry of phosphorus
Organoelement chemistry
Organophosphorus chemistry
Synthesis of chiral phosphorus-containing ligands
1 citation
Aksenov Aleksandr
🥼 🤝
DSc in Chemistry, professor
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h-index: 24
North Caucasus Federal University
North Caucasus Federal University
Research interests
Medicinal Chemistry
Organic Chemistry
1 citation
Sosnovskikh Vyacheslav
DSc in Chemistry, professor
355 publications,  4 721 citations
h-index: 30
Ural Federal University
Ural Federal University
1 citation
Ilkin Vladimir
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h-index: 7
Ural Federal University
Ural Federal University
Research interests
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Heterocyclic compounds
Organic Chemistry
Synthetic Organic Chemistry
1 citation
Birin Kirill
🥼 🤝
DSc in Chemistry
95 publications,  1 189 citations,  2 reviews
h-index: 19
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
MIREA — Russian Technological University
MIREA — Russian Technological University
National Research University Higher School of Economics
National Research University Higher School of Economics
Research interests
Catalysis
Coordination Chemistry
Green chemistry
Hybrid materials
Inorganic Chemistry
Metal-organic coordination polymers
NMR spectroscopy
Organic Chemistry
Organoelement chemistry
Photocatalysis
Photochemistry
Physical Chemistry
Porphyrins
1 citation
Krylov Igor
PhD in Chemistry
78 publications,  1 885 citations,  18 reviews
h-index: 25
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
Research interests
Green chemistry
Organic Chemistry
Organic electrochemistry
Organic synthesis
Photochemistry
Plant protection
1 citation
Tikhomirov Alexander
🥼 🤝
DSc in Chemistry, associate professor
59 publications,  920 citations
h-index: 17
Mendeleev University of Chemical Technology of Russia
Mendeleev University of Chemical Technology of Russia
Gause Institute of New Antibiotics
Gause Institute of New Antibiotics
Research interests
Medicinal Chemistry
1 citation
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54 publications,  534 citations
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A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences
A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences
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Buev Evgeny
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Ural Federal University
Ural Federal University
Research interests
Chemistry of nitrogen-containing heterocycles
Organic Chemistry
Organic synthesis
1 citation
Demina Liudmila
PhD
69 publications,  478 citations
h-index: 12
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
1 citation
Demina Liudmila
80 publications,  526 citations
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GOST Copy
Kroitor A. P. et al. Unexpected formation of a μ-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru3(CO)12 and its catalytic actIVity in carbene transfer reactions // Dalton Transactions. 2017. Vol. 46. No. 45. pp. 15651-15655.
GOST all authors (up to 50) Copy
Kroitor A. P., Cailler L. P., Martynov A. G., Gorbunova Y. G., Tsivadze A., Tsivadze A. Y., Sorokin A. B. Unexpected formation of a μ-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru3(CO)12 and its catalytic actIVity in carbene transfer reactions // Dalton Transactions. 2017. Vol. 46. No. 45. pp. 15651-15655.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/c7dt03703a
UR - https://xlink.rsc.org/?DOI=C7DT03703A
TI - Unexpected formation of a μ-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru3(CO)12 and its catalytic actIVity in carbene transfer reactions
T2 - Dalton Transactions
AU - Kroitor, Andrey P
AU - Cailler, Lucie P.
AU - Martynov, Alexander G.
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan
AU - Tsivadze, Aslan Yu.
AU - Sorokin, Alexander B
PY - 2017
DA - 2017/10/16
PB - Royal Society of Chemistry (RSC)
SP - 15651-15655
IS - 45
VL - 46
PMID - 29085924
SN - 1477-9226
SN - 1477-9234
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Kroitor,
author = {Andrey P Kroitor and Lucie P. Cailler and Alexander G. Martynov and Yulia G. Gorbunova and Aslan Tsivadze and Aslan Yu. Tsivadze and Alexander B Sorokin},
title = {Unexpected formation of a μ-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru3(CO)12 and its catalytic actIVity in carbene transfer reactions},
journal = {Dalton Transactions},
year = {2017},
volume = {46},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://xlink.rsc.org/?DOI=C7DT03703A},
number = {45},
pages = {15651--15655},
doi = {10.1039/c7dt03703a}
}
MLA
Cite this
MLA Copy
Kroitor, Andrey P., et al. “Unexpected formation of a μ-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru3(CO)12 and its catalytic actIVity in carbene transfer reactions.” Dalton Transactions, vol. 46, no. 45, Oct. 2017, pp. 15651-15655. https://xlink.rsc.org/?DOI=C7DT03703A.