volume 19 issue 32 pages 6995-7000

Scalable 18F processing conditions for copper-mediated radiofluorination chemistry facilitate DoE optimization studies and afford an improved synthesis of [18F]olaparib

Publication typeJournal Article
Publication date2021-08-02
scimago Q2
wos Q2
SJR0.600
CiteScore5.2
Impact factor2.7
ISSN14770520, 14770539
PubMed ID:  34351339
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A convenient and scalable base-free method for processing [18F]fluoride as [18F]TBAF is reported and applied to copper-mediated radiofluorination radiosyntheses. A central feature of this method is that a single production of [18F]TBAF can be divided into small aliquots that can be used to perform multiple small-scale reactions in DoE optimization studies. The results of these studies can then be reliably translated to full batch tracer productions using automated synthesizers. The processing method was applied to the DoE optimization of [18F]olaparib, affording the tracer in high radiochemical yields via both manual (%RCY = 78 ± 6%, n = 4 (CMRF step only)) and automated (up to 80% (%RCY); 41% activity yield (%AY)) radiosynthesis procedures.
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GOST Copy
Bowden G. et al. Scalable 18F processing conditions for copper-mediated radiofluorination chemistry facilitate DoE optimization studies and afford an improved synthesis of [18F]olaparib // Organic and Biomolecular Chemistry. 2021. Vol. 19. No. 32. pp. 6995-7000.
GOST all authors (up to 50) Copy
Bowden G., Chailanggar N., Pichler B. J., Maurer A. Scalable 18F processing conditions for copper-mediated radiofluorination chemistry facilitate DoE optimization studies and afford an improved synthesis of [18F]olaparib // Organic and Biomolecular Chemistry. 2021. Vol. 19. No. 32. pp. 6995-7000.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/d1ob00903f
UR - https://xlink.rsc.org/?DOI=D1OB00903F
TI - Scalable 18F processing conditions for copper-mediated radiofluorination chemistry facilitate DoE optimization studies and afford an improved synthesis of [18F]olaparib
T2 - Organic and Biomolecular Chemistry
AU - Bowden, Gregory
AU - Chailanggar, Nantanat
AU - Pichler, Bernd J.
AU - Maurer, Andreas
PY - 2021
DA - 2021/08/02
PB - Royal Society of Chemistry (RSC)
SP - 6995-7000
IS - 32
VL - 19
PMID - 34351339
SN - 1477-0520
SN - 1477-0539
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Bowden,
author = {Gregory Bowden and Nantanat Chailanggar and Bernd J. Pichler and Andreas Maurer},
title = {Scalable 18F processing conditions for copper-mediated radiofluorination chemistry facilitate DoE optimization studies and afford an improved synthesis of [18F]olaparib},
journal = {Organic and Biomolecular Chemistry},
year = {2021},
volume = {19},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://xlink.rsc.org/?DOI=D1OB00903F},
number = {32},
pages = {6995--7000},
doi = {10.1039/d1ob00903f}
}
MLA
Cite this
MLA Copy
Bowden, Gregory, et al. “Scalable 18F processing conditions for copper-mediated radiofluorination chemistry facilitate DoE optimization studies and afford an improved synthesis of [18F]olaparib.” Organic and Biomolecular Chemistry, vol. 19, no. 32, Aug. 2021, pp. 6995-7000. https://xlink.rsc.org/?DOI=D1OB00903F.