CrystEngComm, volume 24, issue 34, pages 6093-6100
Crystal engineering of molecules with through-space α-effect hydrogen bonds: 3a,6 : 7,9a-diepoxybenzo[de]isoquinolines possessing a free amino group
Publication type: Journal Article
Publication date: 2022-08-11
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The existence of a “through-space” alpha-effect is analyzed in all-cis 3a,6 : 4,5 : 7,9a-triepoxy and 3a,6 : 7,9a-diepoxybenzo[de]isoquinolines. It is demonstrated that the H-bonds are enhanced by the α-effect.
Found
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