Dalton Transactions, volume 52, issue 20, pages 6831-6840

Silicon(IV) complexes of octaaryl substituted porphyrazines and corrolazines: Influence of the macrocycle contraction on spectral-luminescence, acid-base and redox properties

Publication type: Journal Article
Publication date: 2023-04-25
scimago Q1
SJR: 0.697
CiteScore: 6.6
Impact factor: 3.5
ISSN: 14779226, 14779234
Inorganic Chemistry
Abstract

Octaaryl-substituted Si(iv) corrolazine complexes, obtained by reductive ring contraction reaction of the appropriate SiPzAr8, exhibit high ability for single oxygen generation. The crucial role of acid in the Pz → Cz transformation is revealed.

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