New Journal of Chemistry, volume 48, issue 15, pages 6848-6856

Synthesis of P,P-bidentate caged phosphines via tungsten pentacarbonyl-promoted cycloaddition reactions of 1-alkyl-1,2-diphospholes

Almaz A Zagidullin 1
, 
Yulia S Ganushevich 2
, 
Denis Korchagin 3
, 
Peter Lönnecke 4
, 
Evamarie Hey-Hawkins 4
, 
Vasili Miluykov 1
1
 
2
 
3
 
4
 
Publication type: Journal Article
Publication date: 2024-03-15
scimago Q2
SJR: 0.521
CiteScore: 5.3
Impact factor: 2.7
ISSN: 11440546, 13699261
Materials Chemistry
General Chemistry
Catalysis
Abstract

Utilizing the W(CO)5 group as a promoter, we have established a straightforward pathway for the conversion of simple 1-alkyl-1,2-diphospholes to P,P’-bidentate caged phosphines via [4+2] cycloaddition reactions. Furthermore, during the...

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