Overlooked impact of surface hydroxylation on the solubility of less-soluble compounds: a case study of CeO2
Anna Romanchuk
1
,
Anastasia D. Konyukhova
1
,
Irina F Seregina
1
,
Roman Svetogorov
1, 3
,
Vladimir K. Ivanov
2, 5
,
3
Publication type: Journal Article
Publication date: 2024-07-05
scimago Q1
wos Q1
SJR: 1.201
CiteScore: 9.8
Impact factor: 5.1
ISSN: 20518153, 20518161
Abstract
Unexpectedly, the solubility of CeO2 nanoparticles (NPs) at 25 °C does not depend on particle size, but is significantly affected by the sample's thermal pre-treatment. The classical interpretation of NPs' solubility proposed by the Gibbs–Thompson or Kelvin equations fails to describe the experimental data on CeO2 solubility obtained in this study. Thermal treatment did not change the samples' morphological characteristics, while slightly affecting NP hydroxylation and local crystallinity. The differences in the solubility of dried and non-treated CeO2 particles were most noticeable at pH < 4, and dissolved cerium concentration was much lower in the case of the dried sample. After prolonged storage (up to 4.5 years) of CeO2 NPs in aqueous media, the solubility of dried samples gradually increased, while for non-treated samples it remained unchanged. Based on the example of CeO2, the dissolution laws of other less soluble nanomaterials should be reconsidered.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
|
|
|
Chemosphere
1 publication, 16.67%
|
|
|
Ultrasonics Sonochemistry
1 publication, 16.67%
|
|
|
Molecules
1 publication, 16.67%
|
|
|
Small
1 publication, 16.67%
|
|
|
Applied Catalysis B: Environmental
1 publication, 16.67%
|
|
|
Small Science
1 publication, 16.67%
|
|
|
1
|
Publishers
|
1
2
3
|
|
|
Elsevier
3 publications, 50%
|
|
|
Wiley
2 publications, 33.33%
|
|
|
MDPI
1 publication, 16.67%
|
|
|
1
2
3
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
6
Total citations:
6
Citations from 2024:
5
(83.34%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Plakhova T. V. et al. Overlooked impact of surface hydroxylation on the solubility of less-soluble compounds: a case study of CeO2 // Environmental Science: Nano. 2024. Vol. 11. No. 8. pp. 3551-3562.
GOST all authors (up to 50)
Copy
Plakhova T. V., Romanchuk A., Konyukhova A. D., Seregina I. F., Baranchikov A. E., Svetogorov R., Terban M. W., Ivanov V. K., Kalmykov S. N. Overlooked impact of surface hydroxylation on the solubility of less-soluble compounds: a case study of CeO2 // Environmental Science: Nano. 2024. Vol. 11. No. 8. pp. 3551-3562.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/d4en00014e
UR - https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85198048631&origin=inward
TI - Overlooked impact of surface hydroxylation on the solubility of less-soluble compounds: a case study of CeO2
T2 - Environmental Science: Nano
AU - Plakhova, Tatiana V
AU - Romanchuk, Anna
AU - Konyukhova, Anastasia D.
AU - Seregina, Irina F
AU - Baranchikov, Alexander E
AU - Svetogorov, Roman
AU - Terban, Maxwell W.
AU - Ivanov, Vladimir K.
AU - Kalmykov, Stepan N.
PY - 2024
DA - 2024/07/05
PB - Royal Society of Chemistry (RSC)
SP - 3551-3562
IS - 8
VL - 11
SN - 2051-8153
SN - 2051-8161
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2024_Plakhova,
author = {Tatiana V Plakhova and Anna Romanchuk and Anastasia D. Konyukhova and Irina F Seregina and Alexander E Baranchikov and Roman Svetogorov and Maxwell W. Terban and Vladimir K. Ivanov and Stepan N. Kalmykov},
title = {Overlooked impact of surface hydroxylation on the solubility of less-soluble compounds: a case study of CeO2},
journal = {Environmental Science: Nano},
year = {2024},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85198048631&origin=inward},
number = {8},
pages = {3551--3562},
doi = {10.1039/d4en00014e}
}
Cite this
MLA
Copy
Plakhova, Tatiana V., et al. “Overlooked impact of surface hydroxylation on the solubility of less-soluble compounds: a case study of CeO2.” Environmental Science: Nano, vol. 11, no. 8, Jul. 2024, pp. 3551-3562. https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85198048631&origin=inward.