Dalton Transactions, issue 21, pages 4039-4050
Metal-catalyzed synthesis of stereoregular polyketones, polyesters, and polycarbonates
1
Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
|
Publication type: Journal Article
Publication date: 2003-10-21
Journal:
Dalton Transactions
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4
ISSN: 14779226, 14779234
DOI:
10.1039/b304690g
Inorganic Chemistry
Abstract
Stereocontrol of the stereogenic centers in the main chain during the synthesis of polyketones, polyesters, and polycarbonates has been reviewed. The examples described may be classified in the following ways. Retention of the configuration which exists in the monomer: as described in the ring opening polymerization of (S,S)-lactide and (R)-β-butyrolactone to give poly[(S)-lactic acid]
(PSLA) and poly[(R)-3-hydroxybutyrate]
(PRHB), respectively. Enantiomer selection either by the catalyst or by the chain-end: presented examples are the synthesis of heterotactic and isotactic PLAs from racemic lactide and the preparation of syndiotactic and isotactic PHBs from a racemic mixture of β-butyrolactone. Selection of enantiotopic sites of a meso monomer by the catalyst or by the chain-end: syndiotactic and heterotactic PLAs from meso-lactide and isotactic poly(epoxide-alt-CO2) from meso-epoxide are the examples described here. Creation of a new stereogenic center upon polymerization starting from prochiral monomers. The catalyst or the chain-end selects one of the two enantiofaces of an α-olefin in the olefin/CO alternating copolymerization to give either isotactic or syndiotactic polyketones. Thus, a variety of stereoregular polymers are now available owing to the remarkable achievements of precise design and synthesis of single-site catalysts.
Top-30
Citations by journals
|
5
10
15
20
25
30
35
|
|
|
Dalton Transactions
31 publications, 20.81%
|
|
|
Organometallics
13 publications, 8.72%
|
|
|
Macromolecules
8 publications, 5.37%
|
|
|
Inorganic Chemistry
7 publications, 4.7%
|
|
|
Journal of Organometallic Chemistry
7 publications, 4.7%
|
|
|
Inorganic Chemistry Communication
4 publications, 2.68%
|
|
|
Angewandte Chemie
4 publications, 2.68%
|
|
|
Angewandte Chemie - International Edition
4 publications, 2.68%
|
|
|
European Journal of Inorganic Chemistry
4 publications, 2.68%
|
|
|
Chemistry - A European Journal
3 publications, 2.01%
|
|
|
Chemical Reviews
3 publications, 2.01%
|
|
|
Journal of the American Chemical Society
3 publications, 2.01%
|
|
|
Chemical Communications
3 publications, 2.01%
|
|
|
Polymer
2 publications, 1.34%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
2 publications, 1.34%
|
|
|
Chinese Journal of Chemistry
2 publications, 1.34%
|
|
|
Applied Organometallic Chemistry
2 publications, 1.34%
|
|
|
Journal of Polymer Science, Part A: Polymer Chemistry
2 publications, 1.34%
|
|
|
ACS Catalysis
2 publications, 1.34%
|
|
|
Advanced Materials Research
2 publications, 1.34%
|
|
|
Current Organic Chemistry
1 publication, 0.67%
|
|
|
Bulletin of the Chemical Society of Japan
1 publication, 0.67%
|
|
|
Main Group Chemistry
1 publication, 0.67%
|
|
|
Frontiers in Chemistry
1 publication, 0.67%
|
|
|
Science China Chemistry
1 publication, 0.67%
|
|
|
European Polymer Journal
1 publication, 0.67%
|
|
|
Computers and Chemical Engineering
1 publication, 0.67%
|
|
|
Polyhedron
1 publication, 0.67%
|
|
|
Coordination Chemistry Reviews
1 publication, 0.67%
|
|
|
5
10
15
20
25
30
35
|
Citations by publishers
|
5
10
15
20
25
30
35
40
|
|
|
American Chemical Society (ACS)
39 publications, 26.17%
|
|
|
Royal Society of Chemistry (RSC)
37 publications, 24.83%
|
|
|
Wiley
32 publications, 21.48%
|
|
|
Elsevier
23 publications, 15.44%
|
|
|
Trans Tech Publications
3 publications, 2.01%
|
|
|
Springer Nature
2 publications, 1.34%
|
|
|
Bentham Science
1 publication, 0.67%
|
|
|
The Chemical Society of Japan
1 publication, 0.67%
|
|
|
IOS Press
1 publication, 0.67%
|
|
|
Frontiers Media S.A.
1 publication, 0.67%
|
|
|
Taylor & Francis
1 publication, 0.67%
|
|
|
Proceedings of the National Academy of Sciences (PNAS)
1 publication, 0.67%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.67%
|
|
|
5
10
15
20
25
30
35
40
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2004,2005,2006,2007,2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","","","","","","","","","","","","","",""],"datasets":[{"label":"Citations number","data":[3,6,9,14,10,13,12,19,6,11,12,5,7,7,3,2,3,1,1,3,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["2.01","4.03","6.04","9.4","6.71","8.72","8.05","12.75","4.03","7.38","8.05","3.36","4.7","4.7","2.01","1.34","2.01","0.67","0.67","2.01","1.34"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Dalton Transactions","Organometallics","Macromolecules","Inorganic Chemistry","Journal of Organometallic Chemistry","Inorganic Chemistry Communication","Angewandte Chemie","Angewandte Chemie - International Edition","European Journal of Inorganic Chemistry","Chemistry - A European Journal","Chemical Reviews","Journal of the American Chemical Society","Chemical Communications","Polymer","Zeitschrift fur Anorganische und Allgemeine Chemie","Chinese Journal of Chemistry","Applied Organometallic Chemistry","Journal of Polymer Science, Part A: Polymer Chemistry","ACS Catalysis","Advanced Materials Research","Current Organic Chemistry","Bulletin of the Chemical Society of Japan","Main Group Chemistry","Frontiers in Chemistry","Science China Chemistry","European Polymer Journal","Computers and Chemical Engineering","Polyhedron","Coordination Chemistry Reviews"],"ids":[8473,1409,20817,24714,11834,22802,25450,19215,15359,24708,13718,4813,9073,19955,18677,7222,11683,10573,4873,25351,16175,20870,20146,6407,14409,17319,2539,21269,13437],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/lZMRu5MhhE0HtEBGlENti9uMMEivcrzFOV6rqpGN_medium.webp","\/storage\/images\/resized\/doUaFUZdxUEQjLi1TwZjGHi8HXYNWWSk04dSC6Xh_medium.webp","\/storage\/images\/resized\/ktSZPrGjOMvauY6mn7jk8bqo3Af0S6abv653w90B_medium.webp","\/storage\/images\/resized\/KqWdDIHwzps3KNMz2kSZBC4SgMnkL3bwEKJqtZ2u_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[31,13,8,7,7,4,4,4,4,3,3,3,3,2,2,2,2,2,2,2,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[20.81,8.72,5.37,4.7,4.7,2.68,2.68,2.68,2.68,2.01,2.01,2.01,2.01,1.34,1.34,1.34,1.34,1.34,1.34,1.34,0.67,0.67,0.67,0.67,0.67,0.67,0.67,0.67,0.67],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Royal Society of Chemistry (RSC)","Wiley","Elsevier","Trans Tech Publications","Springer Nature","Bentham Science","The Chemical Society of Japan","IOS Press","Frontiers Media S.A.","Taylor & Francis","Proceedings of the National Academy of Sciences (PNAS)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,123,11,17,104,8,39,6950,29,208,18,162,9422],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/lZMRu5MhhE0HtEBGlENti9uMMEivcrzFOV6rqpGN_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/doUaFUZdxUEQjLi1TwZjGHi8HXYNWWSk04dSC6Xh_medium.webp","\/storage\/images\/resized\/ktSZPrGjOMvauY6mn7jk8bqo3Af0S6abv653w90B_medium.webp","\/storage\/images\/resized\/KqWdDIHwzps3KNMz2kSZBC4SgMnkL3bwEKJqtZ2u_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/mxFdPe9qujsfvfYfcN0QOclAiYORFb0xrRlwV8gs_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[39,37,32,23,3,2,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[26.17,24.83,21.48,15.44,2.01,1.34,0.67,0.67,0.67,0.67,0.67,0.67,0.67],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2004,2005,2006,2007,2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,1,0,0,0,0,0,0,1,0,0,0,0,0,0,0,0,0,0,0],"percentage":["0","0","0.67","0","0","0","0","0","0","0.67","0","0","0","0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[1,1,0,0,1,1,0,1,0,2,1,0,1,0,0,0,1,0,1,0,0],"percentage":["0.67","0.67","0","0","0.67","0.67","0","0.67","0","1.34","0.67","0","0.67","0","0","0","0.67","0","0.67","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,0,2,0,1,4,3,0,1,3,0,1,0,0,0,1,0,0,0,1],"percentage":["0","0","0","1.34","0","0.67","2.68","2.01","0","0.67","2.01","0","0.67","0","0","0","0.67","0","0","0","0.67"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[2,5,8,9,9,11,7,11,5,7,6,4,5,5,3,2,1,1,0,3,1],"percentage":["1.34","3.36","5.37","6.04","6.04","7.38","4.7","7.38","3.36","4.7","4.03","2.68","3.36","3.36","2.01","1.34","0.67","0.67","0","2.01","0.67"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,3,0,0,1,4,1,0,2,1,0,2,0,0,0,0,0,0,0],"percentage":["0","0","0","2.01","0","0","0.67","2.68","0.67","0","1.34","0.67","0","1.34","0","0","0","0","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2004,2005,2006,2007,2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,1,0,0,1,0,0,0,0,0,0,1,0,0,0,0,0,0,0,0],"percentage":["0","0","0.67","0","0","0.67","0","0","0","0","0","0","0.67","0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,0,2,1,0,0,0,0,1,0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","1.34","0.67","0","0","0","0","0.67","0","0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,1,0,5,4,4,1,6,2,4,5,2,1,2,1,2,1,0,1,0,0],"percentage":["0.67","0.67","0","3.36","2.68","2.68","0.67","4.03","1.34","2.68","3.36","1.34","0.67","1.34","0.67","1.34","0.67","0","0.67","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,5,6,5,6,8,8,8,3,6,5,2,4,3,2,0,2,1,0,3,2],"percentage":["0.67","3.36","4.03","3.36","4.03","5.37","5.37","5.37","2.01","4.03","3.36","1.34","2.68","2.01","1.34","0","1.34","0.67","0","2.01","1.34"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,0,2,4,0,0,1,4,1,1,2,1,0,2,0,0,0,0,0,0,0],"percentage":["0.67","0","1.34","2.68","0","0","0.67","2.68","0.67","0.67","1.34","0.67","0","1.34","0","0","0","0","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Nakano K. et al. Metal-catalyzed synthesis of stereoregular polyketones, polyesters, and polycarbonates // Dalton Transactions. 2003. Vol. 21. pp. 4039-4050.
GOST all authors (up to 50)
Copy
Nakano K., Kosaka N., Hiyama T., Nozaki K. Metal-catalyzed synthesis of stereoregular polyketones, polyesters, and polycarbonates // Dalton Transactions. 2003. Vol. 21. pp. 4039-4050.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/b304690g
UR - https://doi.org/10.1039/b304690g
TI - Metal-catalyzed synthesis of stereoregular polyketones, polyesters, and polycarbonates
T2 - Dalton Transactions
AU - Kosaka, Naoyuki
AU - Nakano, K
AU - Hiyama, T.
AU - Nozaki, Kyoko
PY - 2003
DA - 2003/10/21 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 4039-4050
IS - 21
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex
Copy
@article{2003_Nakano,
author = {Naoyuki Kosaka and K Nakano and T. Hiyama and Kyoko Nozaki},
title = {Metal-catalyzed synthesis of stereoregular polyketones, polyesters, and polycarbonates},
journal = {Dalton Transactions},
year = {2003},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://doi.org/10.1039/b304690g},
number = {21},
pages = {4039--4050},
doi = {10.1039/b304690g}
}