Chemical Society Reviews, volume 40, issue 4, pages 1937
Direct Sp3α-C–H activation and functionalization of alcohol and ether
Publication type: Journal Article
Publication date: 2011-02-02
Journal:
Chemical Society Reviews
Q1
Q1
SJR: 12.511
CiteScore: 80.8
Impact factor: 40.4
ISSN: 03060012, 14604744
General Chemistry
Abstract
Seven kinds of sp(3)α-C-H activation/C-C formation reactions of alcohols and ethers have been reviewed in this tutorial review, from the viewpoint of both methodology and synthetic application, towards the efficiency, chemo-, regio- and stereoselectivity, catalytic system, substrate scope and mechanistic study. Section 2 describes radical-mediated α-C-H activation and addition/elimination of ethers with unsaturated (C=C and C[triple bond]C) species. Sections 3-8 discuss the α-C-H activation and additions of alcohols and/or ethers with unsaturated (C=C, C[triple bond]C, C=O and C=N) compounds, which involve the key processes of radical mediation, carbenoid insertion, 1,5-H-migration, oxidative dehydrogenation coupling, transfer hydrogenative coupling, and metal-mediated C=C insertion into the C-H bond.
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Zhang S. Yu., Zhang F. M., Tu Y. Direct Sp3α-C–H activation and functionalization of alcohol and ether // Chemical Society Reviews. 2011. Vol. 40. No. 4. p. 1937.
GOST all authors (up to 50)
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Zhang S. Yu., Zhang F. M., Tu Y. Direct Sp3α-C–H activation and functionalization of alcohol and ether // Chemical Society Reviews. 2011. Vol. 40. No. 4. p. 1937.
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TY - JOUR
DO - 10.1039/c0cs00063a
UR - https://doi.org/10.1039/c0cs00063a
TI - Direct Sp3α-C–H activation and functionalization of alcohol and ether
T2 - Chemical Society Reviews
AU - Zhang, Shu Yu
AU - Zhang, Fu Min
AU - Tu, Yong-Qiang
PY - 2011
DA - 2011/02/02
PB - Royal Society of Chemistry (RSC)
SP - 1937
IS - 4
VL - 40
SN - 0306-0012
SN - 1460-4744
ER -
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BibTex (up to 50 authors)
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@article{2011_Zhang,
author = {Shu Yu Zhang and Fu Min Zhang and Yong-Qiang Tu},
title = {Direct Sp3α-C–H activation and functionalization of alcohol and ether},
journal = {Chemical Society Reviews},
year = {2011},
volume = {40},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039/c0cs00063a},
number = {4},
pages = {1937},
doi = {10.1039/c0cs00063a}
}
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MLA
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Zhang, Shu Yu., et al. “Direct Sp3α-C–H activation and functionalization of alcohol and ether.” Chemical Society Reviews, vol. 40, no. 4, Feb. 2011, p. 1937. https://doi.org/10.1039/c0cs00063a.