3D quater- and quinquethiophenesilanes as promising electron-donor materials for BHJ photovoltaic cells and photodetectors
E A Kleymyuk
1
,
Pavel A. Troshin
2
,
E A Khakina
2
,
Y L Moskvin
3
,
S M Peregudova
4
,
S. D. Babenko
3
,
T Meyer Friedrichsen
5
,
T. Meyer-Friedrichsen
5
,
4
5
H. C. Starck Clevios GmbH, Research and Development Division, Chempark Leverkusen, Bldg. B202, 51368 Leverkusen, Germany
|
Publication type: Journal Article
Publication date: 2010-10-13
scimago Q1
wos Q1
SJR: 10.529
CiteScore: 44.0
Impact factor: 30.8
ISSN: 17545692, 17545706
Environmental Chemistry
Pollution
Nuclear Energy and Engineering
Renewable Energy, Sustainability and the Environment
Abstract
The synthesis of new soluble tetrasubstituted quater- and quinquethiophenesilanes and their application as donor materials in bulk heterojunction solar cells and photodetectors has been described. The solubility of these compounds is governed by their 3D molecular structure, solubilizing linear n-hexyl (for quaterthiophenesilane), and branched 2-ethylhexyl groups (for quinquethiophenesilane). It was demonstrated that oligothiophenesilanes blended with fullerene derivatives can be used as promising active layer materials in organic bulk heterojunction solar cells. The maximum power conversion efficiency of the devices increased proportionally with the conjugation length of the oligothiophene units and reached 1.0% and 1.4% for quater- and quinquethiophenesilane respectively. Photodetectors based on the oligothiophenesilane/fullerene composites showed unusually high speeds of operation, which suggests another direction for the practical implementation of the three-dimensional organic semiconductor family designed herein.
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Citations from 2024:
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GOST
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Kleymyuk E. A. et al. 3D quater- and quinquethiophenesilanes as promising electron-donor materials for BHJ photovoltaic cells and photodetectors // Energy and Environmental Science. 2010. Vol. 3. No. 12. p. 1941.
GOST all authors (up to 50)
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Kleymyuk E. A., Troshin P. A., Khakina E. A., Luponosov Y. N., Moskvin Y. L., Peregudova S. M., Babenko S. D., Meyer Friedrichsen T., Meyer-Friedrichsen T., Ponomarenko S. 3D quater- and quinquethiophenesilanes as promising electron-donor materials for BHJ photovoltaic cells and photodetectors // Energy and Environmental Science. 2010. Vol. 3. No. 12. p. 1941.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c0ee00174k
UR - https://doi.org/10.1039/c0ee00174k
TI - 3D quater- and quinquethiophenesilanes as promising electron-donor materials for BHJ photovoltaic cells and photodetectors
T2 - Energy and Environmental Science
AU - Kleymyuk, E A
AU - Troshin, Pavel A.
AU - Khakina, E A
AU - Luponosov, Yuriy N.
AU - Moskvin, Y L
AU - Peregudova, S M
AU - Babenko, S. D.
AU - Meyer Friedrichsen, T
AU - Meyer-Friedrichsen, T.
AU - Ponomarenko, S.
PY - 2010
DA - 2010/10/13
PB - Royal Society of Chemistry (RSC)
SP - 1941
IS - 12
VL - 3
SN - 1754-5692
SN - 1754-5706
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Kleymyuk,
author = {E A Kleymyuk and Pavel A. Troshin and E A Khakina and Yuriy N. Luponosov and Y L Moskvin and S M Peregudova and S. D. Babenko and T Meyer Friedrichsen and T. Meyer-Friedrichsen and S. Ponomarenko},
title = {3D quater- and quinquethiophenesilanes as promising electron-donor materials for BHJ photovoltaic cells and photodetectors},
journal = {Energy and Environmental Science},
year = {2010},
volume = {3},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://doi.org/10.1039/c0ee00174k},
number = {12},
pages = {1941},
doi = {10.1039/c0ee00174k}
}
Cite this
MLA
Copy
Kleymyuk, E. A., et al. “3D quater- and quinquethiophenesilanes as promising electron-donor materials for BHJ photovoltaic cells and photodetectors.” Energy and Environmental Science, vol. 3, no. 12, Oct. 2010, p. 1941. https://doi.org/10.1039/c0ee00174k.