Chemical Communications, volume 47, issue 17, pages 5022

Simple synthetic routes to ruthenium–indenylidene olefin metathesis catalysts

César A. Urbina-Blanco ¹

Simone Manzini ¹

Jessica Pérez Gomes ²

Angelino Doppiu ²

Steven P. Nolan ¹

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EastCHEM School of Chemistry, University of St Andrews, St Andrews, UK |

Umicore AG & Co. KG, Rodenbacher Chaussee 4, 63457 Hanau-Wolfgang, Germany |

Publication type: Journal Article

Publication date: 2011-03-21

Royal Society of Chemistry (RSC)

Journal: Chemical Communications

scimago Q1

wos Q2

SJR: 1.133

CiteScore: 8.6

Impact factor: 4.3

ISSN: 13597345, 1364548X

DOI: 10.1039/c1cc10741k

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PubMed ID: 21423960

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

An efficient synthetic protocol involving reactions between the free carbene and [RuCl(2)(PPh(3))(2)(Ind)] followed by addition of pyridine leads to the isolation of olefin metathesis active [RuCl(2)(L)(Py)(Ind)] (L = SIMes and SIPr) complexes. This novel approach circumvents the use of costly tricyclohexylphosphine.

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Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

scimago Q1

wos Q2

SJR

1.133

CiteScore

8.6

Impact factor

4.3

ISSN

13597345 (Print)

1364548X (Electronic)

Profiles

Nolan, Steven P

Simple synthetic routes to ruthenium–indenylidene olefin metathesis catalysts

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