Chemical Communications, volume 47, issue 19, pages 5428-5430

What is the initiation step of the Grubbs-Hoveyda olefinmetathesiscatalyst?

I. Ashworth ¹

Ian H Hillier ²

D J Nelson ³

Jonathan M Percy ³

M.A. Vincent ²

Hide authors affiliations Show authors affiliations: 3 affiliations

AstraZeneca Global Research and Development, Silk Road Business Park, Charter Way, Macclesfield, UK |

School of Chemistry, University of Manchester, Oxford road, Manchester, UK |

WestChem Department of Pure and Applied Chemistry, Thomas Graham Building, 295 Cathedral Street, Glasgow, UK |

Publication type: Journal Article

Publication date: 2011-04-12

Royal Society of Chemistry (RSC)

Journal: Chemical Communications

Quartile SCImago

Quartile WOS

Impact factor: 4.9

ISSN: 13597345, 1364548X

DOI: 10.1039/c1cc11230a

Copy DOI

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

The activation mechanism and associated energetics of the Grubbs-Hoveyda olefin metathesis pre-catalyst have been established via DFT calculations and experiment.

By date By citations

Top-30

Citations by journals

	2 4 6 8 10 12 14 16
Organometallics	Organometallics, 16, 18.6% Organometallics 16 publications, 18.6%
Dalton Transactions	Dalton Transactions, 8, 9.3% Dalton Transactions 8 publications, 9.3%
Journal of the American Chemical Society	Journal of the American Chemical Society, 7, 8.14% Journal of the American Chemical Society 7 publications, 8.14%
ACS Catalysis	ACS Catalysis, 5, 5.81% ACS Catalysis 5 publications, 5.81%
Journal of Organometallic Chemistry	Journal of Organometallic Chemistry, 4, 4.65% Journal of Organometallic Chemistry 4 publications, 4.65%
Chemistry - A European Journal	Chemistry - A European Journal, 4, 4.65% Chemistry - A European Journal 4 publications, 4.65%
Molecular Catalysis	Molecular Catalysis, 2, 2.33% Molecular Catalysis 2 publications, 2.33%
Journal of Organic Chemistry	Journal of Organic Chemistry, 2, 2.33% Journal of Organic Chemistry 2 publications, 2.33%
Journal of Physical Chemistry A	Journal of Physical Chemistry A, 2, 2.33% Journal of Physical Chemistry A 2 publications, 2.33%
Molecules	Molecules, 1, 1.16% Molecules 1 publication, 1.16%
Catalysts	Catalysts, 1, 1.16% Catalysts 1 publication, 1.16%
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry	Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 1, 1.16% Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry 1 publication, 1.16%
Journal of Molecular Modeling	Journal of Molecular Modeling, 1, 1.16% Journal of Molecular Modeling 1 publication, 1.16%
Theoretical Chemistry Accounts	Theoretical Chemistry Accounts, 1, 1.16% Theoretical Chemistry Accounts 1 publication, 1.16%
Inorganica Chimica Acta	Inorganica Chimica Acta, 1, 1.16% Inorganica Chimica Acta 1 publication, 1.16%
Journal of Molecular Catalysis A Chemical	Journal of Molecular Catalysis A Chemical, 1, 1.16% Journal of Molecular Catalysis A Chemical 1 publication, 1.16%
Computational and Theoretical Chemistry	Computational and Theoretical Chemistry, 1, 1.16% Computational and Theoretical Chemistry 1 publication, 1.16%
Catalysis Communications	Catalysis Communications, 1, 1.16% Catalysis Communications 1 publication, 1.16%
Journal of Fluorine Chemistry	Journal of Fluorine Chemistry, 1, 1.16% Journal of Fluorine Chemistry 1 publication, 1.16%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 1.16% Coordination Chemistry Reviews 1 publication, 1.16%
Polyhedron	Polyhedron, 1, 1.16% Polyhedron 1 publication, 1.16%
ChemPhysChem	ChemPhysChem, 1, 1.16% ChemPhysChem 1 publication, 1.16%
Applied Organometallic Chemistry	Applied Organometallic Chemistry, 1, 1.16% Applied Organometallic Chemistry 1 publication, 1.16%
Journal of Computational Chemistry	Journal of Computational Chemistry, 1, 1.16% Journal of Computational Chemistry 1 publication, 1.16%
European Journal of Inorganic Chemistry	European Journal of Inorganic Chemistry, 1, 1.16% European Journal of Inorganic Chemistry 1 publication, 1.16%
European Journal of Organic Chemistry	European Journal of Organic Chemistry, 1, 1.16% European Journal of Organic Chemistry 1 publication, 1.16%
Advanced Synthesis and Catalysis	Advanced Synthesis and Catalysis, 1, 1.16% Advanced Synthesis and Catalysis 1 publication, 1.16%
ACS Macro Letters	ACS Macro Letters, 1, 1.16% ACS Macro Letters 1 publication, 1.16%
Chemical Reviews	Chemical Reviews, 1, 1.16% Chemical Reviews 1 publication, 1.16%
	2 4 6 8 10 12 14 16

Citations by publishers

	5 10 15 20 25 30 35
American Chemical Society (ACS)	American Chemical Society (ACS), 34, 39.53% American Chemical Society (ACS) 34 publications, 39.53%
Wiley	Wiley, 16, 18.6% Wiley 16 publications, 18.6%
Elsevier	Elsevier, 15, 17.44% Elsevier 15 publications, 17.44%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 13, 15.12% Royal Society of Chemistry (RSC) 13 publications, 15.12%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 2.33% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 2.33%
Springer Nature	Springer Nature, 2, 2.33% Springer Nature 2 publications, 2.33%
Society of Synthetic Organic Chemistry	Society of Synthetic Organic Chemistry, 1, 1.16% Society of Synthetic Organic Chemistry 1 publication, 1.16%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.16% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.16%
	5 10 15 20 25 30 35

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","","","","","","",""],"datasets":[{"label":"Citations number","data":[4,12,17,10,8,3,4,5,3,6,5,6,1,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["4.65","13.95","19.77","11.63","9.3","3.49","4.65","5.81","3.49","6.98","5.81","6.98","1.16","2.33"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Organometallics","Dalton Transactions","Journal of the American Chemical Society","ACS Catalysis","Journal of Organometallic Chemistry","Chemistry - A European Journal","Molecular Catalysis","Journal of Organic Chemistry","Journal of Physical Chemistry A","Molecules","Catalysts","Yuki Gosei Kagaku Kyokaishi\/Journal of Synthetic Organic Chemistry","Journal of Molecular Modeling","Theoretical Chemistry Accounts","Inorganica Chimica Acta","Journal of Molecular Catalysis A Chemical","Computational and Theoretical Chemistry","Catalysis Communications","Journal of Fluorine Chemistry","Coordination Chemistry Reviews","Polyhedron","ChemPhysChem","Applied Organometallic Chemistry","Journal of Computational Chemistry","European Journal of Inorganic Chemistry","European Journal of Organic Chemistry","Advanced Synthesis and Catalysis","ACS Macro Letters","Chemical Reviews"],"ids":[1409,8473,4813,4873,11834,24708,4906,8697,15255,1770,3739,3551,6610,19212,1406,25337,12461,23806,14755,13437,21269,16306,11683,423,15359,19472,3906,957,13718],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/QzzkQMUwda0fYU3txrAv3z24JfXJEjptEQpWMERc_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[16,8,7,5,4,4,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[18.6,9.3,8.14,5.81,4.65,4.65,2.33,2.33,2.33,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16,1.16],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Wiley","Elsevier","Royal Society of Chemistry (RSC)","Multidisciplinary Digital Publishing Institute (MDPI)","Springer Nature","Society of Synthetic Organic Chemistry","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,11,17,123,202,8,1303,9422],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/QzzkQMUwda0fYU3txrAv3z24JfXJEjptEQpWMERc_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[34,16,15,13,2,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[39.53,18.6,17.44,15.12,2.33,2.33,1.16,1.16],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0,0,0,1,0,0,0],"percentage":["0","0","0","0","0","0","0","0","0","0","1.16","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,2,1,1,0,0,0,1,0,0,1,0,1],"percentage":["0","1.16","2.33","1.16","1.16","0","0","0","1.16","0","0","1.16","0","1.16"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,1,0,0,2,2,1,2,0,1,1,3,0,0],"percentage":["0","1.16","0","0","2.33","2.33","1.16","2.33","0","1.16","1.16","3.49","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[4,8,14,6,3,1,2,3,2,5,1,1,1,1],"percentage":["4.65","9.3","16.28","6.98","3.49","1.16","2.33","3.49","2.33","5.81","1.16","1.16","1.16","1.16"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,2,1,3,2,0,1,0,0,0,2,1,0,0],"percentage":["0","2.33","1.16","3.49","2.33","0","1.16","0","0","0","2.33","1.16","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,1,0,0,0,0,0,1,0,0,0],"percentage":["0","0","0","0","1.16","0","0","0","0","0","1.16","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1,1,0,0,0,1,0,2,0,0,0,0,0],"percentage":["0","1.16","1.16","0","0","0","1.16","0","2.33","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,8,7,5,2,2,1,3,0,3,2,5,0,1],"percentage":["0","9.3","8.14","5.81","2.33","2.33","1.16","3.49","0","3.49","2.33","5.81","0","1.16"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[4,1,8,2,3,1,1,2,1,3,0,0,1,1],"percentage":["4.65","1.16","9.3","2.33","3.49","1.16","1.16","2.33","1.16","3.49","0","0","1.16","1.16"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,2,1,3,2,0,1,0,0,0,2,1,0,0],"percentage":["0","2.33","1.16","3.49","2.33","0","1.16","0","0","0","2.33","1.16","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Ashworth I. et al. What is the initiation step of the Grubbs-Hoveyda olefinmetathesiscatalyst? // Chemical Communications. 2011. Vol. 47. No. 19. pp. 5428-5430.

GOST all authors (up to 50) Copy

Ashworth I., Hillier I. H., Nelson D. J., Percy J. M., Vincent M. What is the initiation step of the Grubbs-Hoveyda olefinmetathesiscatalyst? // Chemical Communications. 2011. Vol. 47. No. 19. pp. 5428-5430.

RIS |

Cite this