Energetics of the ruthenium–halide bond in olefin metathesis (pre)catalysts
1
2
Publication type: Journal Article
Publication date: 2013-01-01
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
23235534
Inorganic Chemistry
Abstract
A DFT analysis of the strength of the Ru-halide bond in a series of typical olefin metathesis (pre)catalysts is presented. The calculated Ru-halide bond energies span the rather broad window of 25-43 kcal mol(-1). This indicates that in many systems dissociation of the Ru-halide bond is possible and is actually competitive with dissociation of the labile ligand generating the 14e active species. Consequently, formation of cationic Ru species in solution should be considered as a possible event.
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34
Total citations:
34
Citations from 2024:
3
(8.82%)
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GOST
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Falivene L. et al. Energetics of the ruthenium–halide bond in olefin metathesis (pre)catalysts // Dalton Transactions. 2013. Vol. 42. No. 20. pp. 7312-7317.
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Falivene L., Poater A., Cazin C. S. J., Slugovc C., Cavallo L. M. Energetics of the ruthenium–halide bond in olefin metathesis (pre)catalysts // Dalton Transactions. 2013. Vol. 42. No. 20. pp. 7312-7317.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c2dt32277c
UR - https://doi.org/10.1039/c2dt32277c
TI - Energetics of the ruthenium–halide bond in olefin metathesis (pre)catalysts
T2 - Dalton Transactions
AU - Falivene, Laura
AU - Poater, Albert
AU - Cazin, Catherine S. J.
AU - Slugovc, Christian
AU - Cavallo, Luigi Maria
PY - 2013
DA - 2013/01/01
PB - Royal Society of Chemistry (RSC)
SP - 7312-7317
IS - 20
VL - 42
PMID - 23235534
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
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@article{2013_Falivene,
author = {Laura Falivene and Albert Poater and Catherine S. J. Cazin and Christian Slugovc and Luigi Maria Cavallo},
title = {Energetics of the ruthenium–halide bond in olefin metathesis (pre)catalysts},
journal = {Dalton Transactions},
year = {2013},
volume = {42},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c2dt32277c},
number = {20},
pages = {7312--7317},
doi = {10.1039/c2dt32277c}
}
Cite this
MLA
Copy
Falivene, Laura, et al. “Energetics of the ruthenium–halide bond in olefin metathesis (pre)catalysts.” Dalton Transactions, vol. 42, no. 20, Jan. 2013, pp. 7312-7317. https://doi.org/10.1039/c2dt32277c.