Dalton Transactions, volume 42, issue 2, pages 355-358

Intriguing substituent effect in modified Hoveyda–Grubbs metathesis catalysts incorporating a chelating iodo-benzylidene ligand

Michał Barbasiewicz ¹

Krzysztof Błocki ¹

Maura Malinska ¹

Robert Pawłowski ¹

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Faculty of Chemistry, Warsaw University, Pasteura 1, Warsaw, Poland |

Publication type: Journal Article

Publication date: 2013-01-01

Royal Society of Chemistry (RSC)

Journal: Dalton Transactions

scimago Q1

wos Q2

SJR: 0.697

CiteScore: 6.6

Impact factor: 3.5

ISSN: 14779226, 14779234

DOI: 10.1039/c2dt32422a

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PubMed ID: 23160658

Inorganic Chemistry

Abstract

A series of modified Hoveyda-Grubbs catalysts incorporating a chelating iodo-benzylidene ligand were prepared and characterized. The presence of electron-withdrawing ring substituents in the para position to the iodide was found to decrease the catalytic activity, revealing that dissociation of the Ru···I-Ar bond is not the rate-determining step.

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Publisher

Royal Society of Chemistry (RSC)

Journal

Dalton Transactions

scimago Q1

wos Q2

SJR

0.697

CiteScore

6.6

Impact factor

3.5

ISSN

14779226 (Print)

14779234 (Electronic)

Intriguing substituent effect in modified Hoveyda–Grubbs metathesis catalysts incorporating a chelating iodo-benzylidene ligand

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