Journal of the Chemical Society Chemical Communications

, издание 16 , страницы 1099-1101

Organometallic photochemistry in supercritical fluids: the reaction of H₂with [(η⁵-C₅H₅)M(CO)₃](M  Re and Mn) and the formation of a ‘non-classical’dihydrogen complex of manganese(I)

Тип публикации: Journal Article

Дата публикации: 1989-01-01

Royal Society of Chemistry (RSC)

Journal of the Chemical Society Chemical Communications

SJR: —

CiteScore: —

Impact factor: —

ISSN: 00224936

DOI: 10.1039/c39890001099

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Molecular Medicine

Краткое описание

U.v. photolysis of [(cp)M(CO)3](cp =η5-C5H5,M Re and Mn) at room temperature in supercritical Xe pressurized with H2, leads to formation of the dihydride, [(Cp)Re(CO)2H2], and the ‘non-classical’ dihydrogen complex, [(cp)Mn(CO)2(H2)], which is stabilized by the high pressure of H2.

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Howdle S., Poliakoff M. Organometallic photochemistry in supercritical fluids: the reaction of H2with [(η5-C5H5)M(CO)3](M  Re and Mn) and the formation of a ‘non-classical’dihydrogen complex of manganese(I) // Journal of the Chemical Society Chemical Communications. 1989. Vol. 16. pp. 1099-1101.

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TY - JOUR

DO - 10.1039/c39890001099

UR - https://doi.org/10.1039/c39890001099

TI - Organometallic photochemistry in supercritical fluids: the reaction of H2with [(η5-C5H5)M(CO)3](M  Re and Mn) and the formation of a ‘non-classical’dihydrogen complex of manganese(I)

T2 - Journal of the Chemical Society Chemical Communications

AU - Howdle, S.

AU - Poliakoff, Martyn

PY - 1989

DA - 1989/01/01

PB - Royal Society of Chemistry (RSC)

SP - 1099-1101

IS - 16

SN - 0022-4936

ER -

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@article{1989_Howdle,

author = {S. Howdle and Martyn Poliakoff},

title = {Organometallic photochemistry in supercritical fluids: the reaction of H2with [(η5-C5H5)M(CO)3](M  Re and Mn) and the formation of a ‘non-classical’dihydrogen complex of manganese(I)},

journal = {Journal of the Chemical Society Chemical Communications},

year = {1989},

publisher = {Royal Society of Chemistry (RSC)},

month = {jan},

url = {https://doi.org/10.1039/c39890001099},

number = {16},

pages = {1099--1101},

doi = {10.1039/c39890001099}

}

Издатель

Royal Society of Chemistry (RSC)

Журнал

Journal of the Chemical Society Chemical Communications

SJR

—

CiteScore

—

Impact factor

—

ISSN

00224936 (Print)