Highly selective partial oxidation of methane to methyl trifluoroacetate
Publication type: Journal Article
Publication date: 1990-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00224936
Molecular Medicine
Abstract
Methane has been oxidized stoicheiometrically by cobalt(III) trifluoroacetate in CF3CO2H solution at 150–180 °C and 10–40 atm to give methyl trifluoroacetate in 90 ± 10% yield based on CoIII, which is reduced to CoII; in the presence of O2(1–5 atm) the reaction becomes catalytic with respect to the cobalt(III) salt, giving methyl trifluoroacetate as the sole product of the oxidation of methane by dioxygen.
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Metrics
93
Total citations:
93
Citations from 2024:
6
(6.45%)
Cite this
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RIS |
BibTex
Cite this
GOST
Copy
Vargaftik M. et al. Highly selective partial oxidation of methane to methyl trifluoroacetate // Journal of the Chemical Society Chemical Communications. 1990. Vol. 15. pp. 1049-1050.
GOST all authors (up to 50)
Copy
Vargaftik M., Vargaftik M., Stolarov I., Stolarov I. P., Moiseev I. I., Moiseev I. I. Highly selective partial oxidation of methane to methyl trifluoroacetate // Journal of the Chemical Society Chemical Communications. 1990. Vol. 15. pp. 1049-1050.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/C39900001049
UR - https://xlink.rsc.org/?DOI=c39900001049
TI - Highly selective partial oxidation of methane to methyl trifluoroacetate
T2 - Journal of the Chemical Society Chemical Communications
AU - Vargaftik, Michael
AU - Vargaftik, M.N.
AU - Stolarov, Igor
AU - Stolarov, I P
AU - Moiseev, Ilya I
AU - Moiseev, I. I.
PY - 1990
DA - 1990/01/01
PB - Royal Society of Chemistry (RSC)
SP - 1049-1050
IS - 15
SN - 0022-4936
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1990_Vargaftik,
author = {Michael Vargaftik and M.N. Vargaftik and Igor Stolarov and I P Stolarov and Ilya I Moiseev and I. I. Moiseev},
title = {Highly selective partial oxidation of methane to methyl trifluoroacetate},
journal = {Journal of the Chemical Society Chemical Communications},
year = {1990},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=c39900001049},
number = {15},
pages = {1049--1050},
doi = {10.1039/C39900001049}
}