Arene-catalysed lithiation reactions with lithium at low temperature
Тип публикации: Journal Article
Дата публикации: 1991-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00224936
Molecular Medicine
Краткое описание
The reaction of functionalized alkyl chlorides or phenyl sulphides with an excess of lithium powder in the presence of a catalytic amount of an arene (1%; naphthalene, biphenyl, 4,4′-di-tert-butylbiphenyl) in tetrahydrofuran (THF) at –78 °C gives the corresponding organolithium compounds, which react with electrophiles such as water, iso-butyraldehyde, or cyclohexanone to yield the expected reaction products.
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ГОСТ
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Yus M., Ramón D. Arene-catalysed lithiation reactions with lithium at low temperature // Journal of the Chemical Society Chemical Communications. 1991. Vol. 6. pp. 398-400.
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Yus M., Ramón D. Arene-catalysed lithiation reactions with lithium at low temperature // Journal of the Chemical Society Chemical Communications. 1991. Vol. 6. pp. 398-400.
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TY - JOUR
DO - 10.1039/C39910000398
UR - https://doi.org/10.1039/C39910000398
TI - Arene-catalysed lithiation reactions with lithium at low temperature
T2 - Journal of the Chemical Society Chemical Communications
AU - Yus, Miguel
AU - Ramón, Diego
PY - 1991
DA - 1991/01/01
PB - Royal Society of Chemistry (RSC)
SP - 398-400
IS - 6
SN - 0022-4936
ER -
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@article{1991_Yus,
author = {Miguel Yus and Diego Ramón},
title = {Arene-catalysed lithiation reactions with lithium at low temperature},
journal = {Journal of the Chemical Society Chemical Communications},
year = {1991},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/C39910000398},
number = {6},
pages = {398--400},
doi = {10.1039/C39910000398}
}