Chemical Communications

, volume 49 , issue 35 , pages 3700

Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

Qicai Xue ¹

Jin Xie ¹

Huamin Li ¹

Yixiang Cheng ¹

Chengjian Zhu ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of China |

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 200032, People's Republic of China |

Publication type: Journal Article

Publication date: 2013-03-15

Royal Society of Chemistry (RSC)

Chemical Communications

scimago Q1

wos Q2

SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/c3cc41558a

Copy DOI

PubMed ID: 23536004

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

A new synthetic approach toward direct C-N bond formation through sp(3) C-H activation has been developed under metal-free conditions. Both primary and secondary benzylic C-H substrates could react smoothly with various amines to give only mono-amination products with good to excellent yields.

Found

1 citation

Budnikova Yulia

DSc in Chemistry, professor

259 publications, 4 512 citations, 54 reviews

h-index: 34

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Research interests

C-H functionalization

Catalysis

Charge transfer

Chemistry of organoelement compounds

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Cite this

GOST |

Cite this

GOST Copy

Xue Q. et al. Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds // Chemical Communications. 2013. Vol. 49. No. 35. p. 3700.

GOST all authors (up to 50) Copy

Xue Q., Xie J., Li H., Cheng Y., Zhu C. Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds // Chemical Communications. 2013. Vol. 49. No. 35. p. 3700.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1039/c3cc41558a

UR - https://doi.org/10.1039/c3cc41558a

TI - Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

T2 - Chemical Communications

AU - Xue, Qicai

AU - Xie, Jin

AU - Li, Huamin

AU - Cheng, Yixiang

AU - Zhu, Chengjian

PY - 2013

DA - 2013/03/15

PB - Royal Society of Chemistry (RSC)

SP - 3700

IS - 35

VL - 49

PMID - 23536004

SN - 1359-7345

SN - 1364-548X

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2013_Xue,

author = {Qicai Xue and Jin Xie and Huamin Li and Yixiang Cheng and Chengjian Zhu},

title = {Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds},

journal = {Chemical Communications},

year = {2013},

volume = {49},

publisher = {Royal Society of Chemistry (RSC)},

month = {mar},

url = {https://doi.org/10.1039/c3cc41558a},

number = {35},

pages = {3700},

doi = {10.1039/c3cc41558a}

}

MLA

Cite this

MLA Copy

Xue, Qicai, et al. “Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds.” Chemical Communications, vol. 49, no. 35, Mar. 2013, p. 3700. https://doi.org/10.1039/c3cc41558a.

Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

scimago Q1

wos Q2

SJR

1.037

CiteScore

7.4

Impact factor

4.2

ISSN

13597345 (Print)

1364548X (Electronic)