Intramolecular donor–acceptor cyclopropane ring-opening cyclizations
Publication type: Journal Article
Publication date: 2014-01-01
scimago Q1
wos Q1
SJR: 11.467
CiteScore: 73.2
Impact factor: 39.0
ISSN: 03060012, 14604744
PubMed ID:
24257068
General Chemistry
Abstract
Cyclization reactions of donor-acceptor (D-A) cyclopropanes are recognized as versatile methods for construction of carbocyclic and heterocyclic scaffolds. In the literature, many examples of these polarized cyclopropanes' reactivity with nucleophiles, electrophiles, and radicals are prevalent. Although intermolecular reactivity of donor-acceptor cyclopropanes is widely reported, reviews that center on their intramolecular chemistry are rare. Thereupon, this tutorial review focalizes on new intramolecular transformations of donor-acceptor cyclopropanes for cycloisomerizations, formal cycloadditions, umpolung reactions, rearrangements and ring-opening lactonizations/lactamizations from 2009 to 2013. Furthermore, the role of D-A acceptor cyclopropanes as reactive subunits in natural product synthesis is underscored.
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720
Total citations:
720
Citations from 2024:
89
(12%)
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GOST
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Cavitt M. A., Phun L. H., France S. Intramolecular donor–acceptor cyclopropane ring-opening cyclizations // Chemical Society Reviews. 2014. Vol. 43. No. 3. pp. 804-818.
GOST all authors (up to 50)
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Cavitt M. A., Phun L. H., France S. Intramolecular donor–acceptor cyclopropane ring-opening cyclizations // Chemical Society Reviews. 2014. Vol. 43. No. 3. pp. 804-818.
Cite this
RIS
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TY - JOUR
DO - 10.1039/C3CS60238A
UR - https://doi.org/10.1039/C3CS60238A
TI - Intramolecular donor–acceptor cyclopropane ring-opening cyclizations
T2 - Chemical Society Reviews
AU - Cavitt, Marchello A
AU - Phun, Lien H
AU - France, Stefan
PY - 2014
DA - 2014/01/01
PB - Royal Society of Chemistry (RSC)
SP - 804-818
IS - 3
VL - 43
PMID - 24257068
SN - 0306-0012
SN - 1460-4744
ER -
Cite this
BibTex (up to 50 authors)
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@article{2014_Cavitt,
author = {Marchello A Cavitt and Lien H Phun and Stefan France},
title = {Intramolecular donor–acceptor cyclopropane ring-opening cyclizations},
journal = {Chemical Society Reviews},
year = {2014},
volume = {43},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/C3CS60238A},
number = {3},
pages = {804--818},
doi = {10.1039/C3CS60238A}
}
Cite this
MLA
Copy
Cavitt, Marchello A., et al. “Intramolecular donor–acceptor cyclopropane ring-opening cyclizations.” Chemical Society Reviews, vol. 43, no. 3, Jan. 2014, pp. 804-818. https://doi.org/10.1039/C3CS60238A.