A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries
Yoshikatsu Seino
1
,
Ota Tsuyoshi
1
,
Kazunori Takada
2
,
Akitoshi Hayashi
3
,
Masahiro Tatsumisago
3
1
Idemitsu Kosan Co. Ltd., Kami-izumi 1280, Sodegaura, Chiba, Japan
|
Publication type: Journal Article
Publication date: 2014-01-01
scimago Q1
wos Q1
SJR: 10.529
CiteScore: 44.0
Impact factor: 30.8
ISSN: 17545692, 17545706
Environmental Chemistry
Pollution
Nuclear Energy and Engineering
Renewable Energy, Sustainability and the Environment
Abstract
We report that a heat-treated Li2S–P2S5 glass-ceramic conductor has an extremely high ionic conductivity of 1.7 × 10−2 S cm−1 and the lowest conduction activation energy of 17 kJ mol−1 at room temperature among lithium-ion conductors reported to date. The optimum conditions of the heat treatment reduce the grain boundary resistance, and the influence of voids, to increase the Li+ ionic conductivity of the solid electrolyte so that it is greater than the conductivities of liquid electrolytes, when the transport number of lithium ions in the inorganic electrolyte is unity.
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GOST
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Seino Y. et al. A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries // Energy and Environmental Science. 2014. Vol. 7. No. 2. pp. 627-631.
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Seino Y., Tsuyoshi O., Takada K., Hayashi A., Tatsumisago M. A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries // Energy and Environmental Science. 2014. Vol. 7. No. 2. pp. 627-631.
Cite this
RIS
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TY - JOUR
DO - 10.1039/C3EE41655K
UR - https://doi.org/10.1039/C3EE41655K
TI - A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries
T2 - Energy and Environmental Science
AU - Seino, Yoshikatsu
AU - Tsuyoshi, Ota
AU - Takada, Kazunori
AU - Hayashi, Akitoshi
AU - Tatsumisago, Masahiro
PY - 2014
DA - 2014/01/01
PB - Royal Society of Chemistry (RSC)
SP - 627-631
IS - 2
VL - 7
SN - 1754-5692
SN - 1754-5706
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Seino,
author = {Yoshikatsu Seino and Ota Tsuyoshi and Kazunori Takada and Akitoshi Hayashi and Masahiro Tatsumisago},
title = {A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries},
journal = {Energy and Environmental Science},
year = {2014},
volume = {7},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/C3EE41655K},
number = {2},
pages = {627--631},
doi = {10.1039/C3EE41655K}
}
Cite this
MLA
Copy
Seino, Yoshikatsu, et al. “A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries.” Energy and Environmental Science, vol. 7, no. 2, Jan. 2014, pp. 627-631. https://doi.org/10.1039/C3EE41655K.
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