Journal of Materials Chemistry A, volume 2, issue 15, pages 5470-5480
Novel Li3ClO based glasses with superionic properties for lithium batteries
1
CEMUC and Engineering Physics Department, Engineering Faculty, Porto University, Portugal
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2
Energy and Geology National Laboratory, S. Mamede Infesta, Portugal
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3
Engineering Physics Department, Engineering Faculty, Porto University, Portugal
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4
CFP and Engineering Physics Department, Engineering Faculty, Porto University, Portugal
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Publication type: Journal Article
Publication date: 2014-03-07
Journal:
Journal of Materials Chemistry A
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 11.9
ISSN: 20507488, 20507496, 09599428, 13645501
General Chemistry
General Materials Science
Renewable Energy, Sustainability and the Environment
Abstract
Three types of next generation batteries are currently being envisaged among the international community: metal-air batteries, multivalent cation batteries and all-solid-state batteries. These battery designs require high-performance, safe and cost effective electrolytes that are compatible with optimized electrode materials. Solid electrolytes have not yet been extensively employed in commercial batteries as they suffer from poor ionic conduction at acceptable temperatures and insufficient stability with respect to lithium-metal. Here we show a novel type of glasses, which evolve from an antiperovskite structure and that show the highest ionic conductivity ever reported for the Li-ion (25 mS cm−1 at 25 °C). These glassy electrolytes for lithium batteries are inexpensive, light, recyclable, non-flammable and non-toxic. Moreover, they present a wide electrochemical window (higher than 8 V) and thermal stability within the application range of temperatures.
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Citations by publishers
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1 publication, 0.63%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Braga M. H. et al. Novel Li3ClO based glasses with superionic properties for lithium batteries // Journal of Materials Chemistry A. 2014. Vol. 2. No. 15. pp. 5470-5480.
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Braga M. H., Ferreira J. A., Stockhausen V., Menezes R., El-Azab, A. Novel Li3ClO based glasses with superionic properties for lithium batteries // Journal of Materials Chemistry A. 2014. Vol. 2. No. 15. pp. 5470-5480.
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TY - JOUR
DO - 10.1039/C3TA15087A
UR - https://doi.org/10.1039/C3TA15087A
TI - Novel Li3ClO based glasses with superionic properties for lithium batteries
T2 - Journal of Materials Chemistry A
AU - Ferreira, J. A.
AU - Stockhausen, V
AU - Braga, Maria Helena
AU - Menezes, R.
AU - El-Azab,, Anter
PY - 2014
DA - 2014/03/07 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 5470-5480
IS - 15
VL - 2
SN - 2050-7488
SN - 2050-7496
SN - 0959-9428
SN - 1364-5501
ER -
Cite this
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@article{2014_Braga,
author = {J. A. Ferreira and V Stockhausen and Maria Helena Braga and R. Menezes and Anter El-Azab,},
title = {Novel Li3ClO based glasses with superionic properties for lithium batteries},
journal = {Journal of Materials Chemistry A},
year = {2014},
volume = {2},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://doi.org/10.1039/C3TA15087A},
number = {15},
pages = {5470--5480},
doi = {10.1039/C3TA15087A}
}
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MLA
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Braga, Maria Helena, et al. “Novel Li3ClO based glasses with superionic properties for lithium batteries.” Journal of Materials Chemistry A, vol. 2, no. 15, Mar. 2014, pp. 5470-5480. https://doi.org/10.1039/C3TA15087A.
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