, volume 50 , issue 78 , pages 11454-11457

Catalytic hydroxylation of benzene and toluene by an iron complex bearing a chelating di-pyridyl-di-NHC ligand

Andreas Raba ¹

Mirza Cokoja ¹

Wolfgang A. Herrmann ¹

Fritz Kühn ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Chair of Inorganic Chemistry/Molecular Catalysis, Catalysis Research Center, Technische Universität München, Ernst-Otto-Fischer-Straße 1, D-85747 Garching bei München, Germany |

Publication type: Journal Article

Publication date: 2014-05-20

Royal Society of Chemistry (RSC)

Chemical Communications

scimago Q1

wos Q2

SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/C4CC02178A

Copy DOI

PubMed ID: 24840886

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

This work reports on iron-catalysed hydroxylation of benzene and toluene using aqueous H2O2. While benzene is hydroxylated with a high selectivity to phenol, toluene is hydroxylated to cresols with a high selectivity for the ortho and para-position. An inverse KIE indicates the presence of a high valent Fe=O species during catalysis.

Found

5 citations

Bryliakov Konstantin

DSc in Chemistry

188 publications, 7 721 citations, 75 reviews

h-index: 47

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Transition metal complexes

1 citation

M. Ana

92 publications, 1 959 citations

h-index: 24

University of Lisbon

Top-30

Journals

	1 2 3 4 5 6 7
Journal of Catalysis	Journal of Catalysis, 7, 7.45% Journal of Catalysis 7 publications, 7.45%
Dalton Transactions	Dalton Transactions, 7, 7.45% Dalton Transactions 7 publications, 7.45%
Catalysis Science and Technology	Catalysis Science and Technology, 7, 7.45% Catalysis Science and Technology 7 publications, 7.45%
RSC Advances	RSC Advances, 5, 5.32% RSC Advances 5 publications, 5.32%
ACS Catalysis	ACS Catalysis, 4, 4.26% ACS Catalysis 4 publications, 4.26%
Inorganic Chemistry	Inorganic Chemistry, 4, 4.26% Inorganic Chemistry 4 publications, 4.26%
Journal of the American Chemical Society	Journal of the American Chemical Society, 4, 4.26% Journal of the American Chemical Society 4 publications, 4.26%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 3, 3.19% Coordination Chemistry Reviews 3 publications, 3.19%
ChemCatChem	ChemCatChem, 2, 2.13% ChemCatChem 2 publications, 2.13%
Catalysts	Catalysts, 2, 2.13% Catalysts 2 publications, 2.13%
Molecular Catalysis	Molecular Catalysis, 2, 2.13% Molecular Catalysis 2 publications, 2.13%
European Journal of Inorganic Chemistry	European Journal of Inorganic Chemistry, 2, 2.13% European Journal of Inorganic Chemistry 2 publications, 2.13%
Chemie in Unserer Zeit	Chemie in Unserer Zeit, 2, 2.13% Chemie in Unserer Zeit 2 publications, 2.13%
Chemistry - A European Journal	Chemistry - A European Journal, 2, 2.13% Chemistry - A European Journal 2 publications, 2.13%
Angewandte Chemie	Angewandte Chemie, 2, 2.13% Angewandte Chemie 2 publications, 2.13%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 2, 2.13% Angewandte Chemie - International Edition 2 publications, 2.13%
Organometallics	Organometallics, 2, 2.13% Organometallics 2 publications, 2.13%
Processes	Processes, 1, 1.06% Processes 1 publication, 1.06%
Frontiers in Chemistry	Frontiers in Chemistry, 1, 1.06% Frontiers in Chemistry 1 publication, 1.06%
Cellulose	Cellulose, 1, 1.06% Cellulose 1 publication, 1.06%
Journal of Porous Materials	Journal of Porous Materials, 1, 1.06% Journal of Porous Materials 1 publication, 1.06%
Chemical Research in Chinese Universities	Chemical Research in Chinese Universities, 1, 1.06% Chemical Research in Chinese Universities 1 publication, 1.06%
Nature Communications	Nature Communications, 1, 1.06% Nature Communications 1 publication, 1.06%
Materials Today Sustainability	Materials Today Sustainability, 1, 1.06% Materials Today Sustainability 1 publication, 1.06%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 1.06% Chemical Engineering Journal 1 publication, 1.06%
Applied Catalysis A: General	Applied Catalysis A: General, 1, 1.06% Applied Catalysis A: General 1 publication, 1.06%
Electrochimica Acta	Electrochimica Acta, 1, 1.06% Electrochimica Acta 1 publication, 1.06%
Journal of Molecular Catalysis A Chemical	Journal of Molecular Catalysis A Chemical, 1, 1.06% Journal of Molecular Catalysis A Chemical 1 publication, 1.06%
Applied Surface Science	Applied Surface Science, 1, 1.06% Applied Surface Science 1 publication, 1.06%
	1 2 3 4 5 6 7

Publishers

	5 10 15 20 25
Elsevier	Elsevier, 24, 25.53% Elsevier 24 publications, 25.53%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 24, 25.53% Royal Society of Chemistry (RSC) 24 publications, 25.53%
Wiley	Wiley, 20, 21.28% Wiley 20 publications, 21.28%
American Chemical Society (ACS)	American Chemical Society (ACS), 15, 15.96% American Chemical Society (ACS) 15 publications, 15.96%
Springer Nature	Springer Nature, 5, 5.32% Springer Nature 5 publications, 5.32%
MDPI	MDPI, 3, 3.19% MDPI 3 publications, 3.19%
Frontiers Media S.A.	Frontiers Media S.A., 1, 1.06% Frontiers Media S.A. 1 publication, 1.06%
Taylor & Francis	Taylor & Francis, 1, 1.06% Taylor & Francis 1 publication, 1.06%
OOO Zhurnal "Mendeleevskie Soobshcheniya"	OOO Zhurnal "Mendeleevskie Soobshcheniya", 1, 1.06% OOO Zhurnal "Mendeleevskie Soobshcheniya" 1 publication, 1.06%
	5 10 15 20 25

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Raba A. et al. Catalytic hydroxylation of benzene and toluene by an iron complex bearing a chelating di-pyridyl-di-NHC ligand // Chemical Communications. 2014. Vol. 50. No. 78. pp. 11454-11457.

GOST all authors (up to 50) Copy

Raba A., Cokoja M., Herrmann W. A., Kühn F. Catalytic hydroxylation of benzene and toluene by an iron complex bearing a chelating di-pyridyl-di-NHC ligand // Chemical Communications. 2014. Vol. 50. No. 78. pp. 11454-11457.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1039/C4CC02178A

UR - https://doi.org/10.1039/C4CC02178A

TI - Catalytic hydroxylation of benzene and toluene by an iron complex bearing a chelating di-pyridyl-di-NHC ligand

T2 - Chemical Communications

AU - Raba, Andreas

AU - Cokoja, Mirza

AU - Herrmann, Wolfgang A.

AU - Kühn, Fritz

PY - 2014

DA - 2014/05/20

PB - Royal Society of Chemistry (RSC)

SP - 11454-11457

IS - 78

VL - 50

PMID - 24840886

SN - 1359-7345

SN - 1364-548X

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2014_Raba,

author = {Andreas Raba and Mirza Cokoja and Wolfgang A. Herrmann and Fritz Kühn},

title = {Catalytic hydroxylation of benzene and toluene by an iron complex bearing a chelating di-pyridyl-di-NHC ligand},

journal = {Chemical Communications},

year = {2014},

volume = {50},

publisher = {Royal Society of Chemistry (RSC)},

month = {may},

url = {https://doi.org/10.1039/C4CC02178A},

number = {78},

pages = {11454--11457},

doi = {10.1039/C4CC02178A}

}

MLA

Cite this

MLA Copy

Raba, Andreas, et al. “Catalytic hydroxylation of benzene and toluene by an iron complex bearing a chelating di-pyridyl-di-NHC ligand.” Chemical Communications, vol. 50, no. 78, May. 2014, pp. 11454-11457. https://doi.org/10.1039/C4CC02178A.

Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

scimago Q1

wos Q2

SJR

1.037

CiteScore

7.4

Impact factor

4.2

ISSN

13597345 (Print)

1364548X (Electronic)