Novel polymer synthesis methodologies using combination of thermally and photochemically-induced nitroxide mediated polymerisation
Jason Morris
1, 2
,
Sofia Telitel
3
,
Kathryn E. Fairfull-Smith
2
,
Steven Bottle
2
,
Jacques Lalevee
3
,
Jean-Louis Clément
1
,
Didier Gigmes
1
3
Institut de Science des Matériaux de Mulhouse IS2M, UMR CNRS 7361, UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, France
|
Publication type: Journal Article
Publication date: 2015-01-01
scimago Q1
wos Q2
SJR: 0.842
CiteScore: 7.6
Impact factor: 3.9
ISSN: 17599954, 17599962
Organic Chemistry
Biochemistry
Polymers and Plastics
Bioengineering
Abstract
The combination of thermally- and photochemically-induced polymerization using light sensitive alkoxyamines was investigated. The thermally driven polymerizations were performed via the cleavage of the alkoxyamine functionality, whereas the photochemically-induced polymerizations were carried out either by nitroxide mediated photo-polymerization (NMP2) or by a classical type II mechanism, depending on the structure of the light-sensitive alkoxyamine employed. Once the potential of the various structures as initiators of thermally- and photo-induced polymerizations was established, their use in combination for block copolymer syntheses was investigated. With each alkoxyamine investigated, block copolymers were successfully obtained and the system was applied to the post-modification of polymer coatings for application in patterning and photografting.
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Total citations:
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Citations from 2025:
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MLA
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GOST
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Morris J. et al. Novel polymer synthesis methodologies using combination of thermally and photochemically-induced nitroxide mediated polymerisation // Polymer Chemistry. 2015. Vol. 6. No. 5. pp. 754-763.
GOST all authors (up to 50)
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Morris J., Telitel S., Fairfull-Smith K. E., Bottle S., Lalevee J., Clément J., Guillaneuf Y., Gigmes D. Novel polymer synthesis methodologies using combination of thermally and photochemically-induced nitroxide mediated polymerisation // Polymer Chemistry. 2015. Vol. 6. No. 5. pp. 754-763.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/C4PY01270D
UR - https://doi.org/10.1039/C4PY01270D
TI - Novel polymer synthesis methodologies using combination of thermally and photochemically-induced nitroxide mediated polymerisation
T2 - Polymer Chemistry
AU - Morris, Jason
AU - Telitel, Sofia
AU - Fairfull-Smith, Kathryn E.
AU - Bottle, Steven
AU - Lalevee, Jacques
AU - Clément, Jean-Louis
AU - Guillaneuf, Yohann
AU - Gigmes, Didier
PY - 2015
DA - 2015/01/01
PB - Royal Society of Chemistry (RSC)
SP - 754-763
IS - 5
VL - 6
SN - 1759-9954
SN - 1759-9962
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Morris,
author = {Jason Morris and Sofia Telitel and Kathryn E. Fairfull-Smith and Steven Bottle and Jacques Lalevee and Jean-Louis Clément and Yohann Guillaneuf and Didier Gigmes},
title = {Novel polymer synthesis methodologies using combination of thermally and photochemically-induced nitroxide mediated polymerisation},
journal = {Polymer Chemistry},
year = {2015},
volume = {6},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/C4PY01270D},
number = {5},
pages = {754--763},
doi = {10.1039/C4PY01270D}
}
Cite this
MLA
Copy
Morris, Jason, et al. “Novel polymer synthesis methodologies using combination of thermally and photochemically-induced nitroxide mediated polymerisation.” Polymer Chemistry, vol. 6, no. 5, Jan. 2015, pp. 754-763. https://doi.org/10.1039/C4PY01270D.
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