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RSC Advances, volume 4, issue 92, pages 50361-50364

Azo substituted 1,2,4-oxadiazoles as insensitive energetic materials

Venugopal Thottempudi 1
Chunlin He 1
1
 
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343, USA
Publication typeJournal Article
Publication date2014-10-01
Journal: RSC Advances
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor3.9
ISSN20462069, 20462069
General Chemistry
General Chemical Engineering
Abstract
5,5′-Diamino-3,3′-azo-1,2,4-oxadiazole (3) was synthesized by reacting 3,5-diamino-1,2,4-oxadiazole with potassium permanganate in the presence of an organic solvent. Nitration of 5-amino-3-azo-1,2,4-oxadiazole gave rise to the 1,2,4-oxadiazolone (4) directly rather than the nitramine compound. Energetic salts of oxadiazolone 4 were prepared by treating with amine bases. These high nitrogen compounds were fully characterized using IR and multinuclear NMR spectroscopy, elemental analysis, and differential scanning calorimetry (DSC), and, in case of 3, with single crystal X-ray structuring. All the azo-substituted 1,2,4-oxadiazoles are impact insensitive materials.

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GOST |
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GOST Copy
Thottempudi V. et al. Azo substituted 1,2,4-oxadiazoles as insensitive energetic materials // RSC Advances. 2014. Vol. 4. No. 92. pp. 50361-50364.
GOST all authors (up to 50) Copy
Thottempudi V., Zhang J., He C., Shreeve J. M. Azo substituted 1,2,4-oxadiazoles as insensitive energetic materials // RSC Advances. 2014. Vol. 4. No. 92. pp. 50361-50364.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/C4RA10821C
UR - https://doi.org/10.1039/C4RA10821C
TI - Azo substituted 1,2,4-oxadiazoles as insensitive energetic materials
T2 - RSC Advances
AU - Thottempudi, Venugopal
AU - Zhang, Jiaheng
AU - He, Chunlin
AU - Shreeve, Jean'ne M.
PY - 2014
DA - 2014/10/01 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 50361-50364
IS - 92
VL - 4
SN - 2046-2069
SN - 2046-2069
ER -
BibTex |
Cite this
BibTex Copy
@article{2014_Thottempudi,
author = {Venugopal Thottempudi and Jiaheng Zhang and Chunlin He and Jean'ne M. Shreeve},
title = {Azo substituted 1,2,4-oxadiazoles as insensitive energetic materials},
journal = {RSC Advances},
year = {2014},
volume = {4},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://doi.org/10.1039/C4RA10821C},
number = {92},
pages = {50361--50364},
doi = {10.1039/C4RA10821C}
}
MLA
Cite this
MLA Copy
Thottempudi, Venugopal, et al. “Azo substituted 1,2,4-oxadiazoles as insensitive energetic materials.” RSC Advances, vol. 4, no. 92, Oct. 2014, pp. 50361-50364. https://doi.org/10.1039/C4RA10821C.
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