Chemical Communications

, volume 51 , issue 54 , pages 10907-10909

Acrylate formation from CO₂ and ethylene: catalysis with palladium and mechanistic insight

S Chantal E Stieber ¹

Núria Huguet ¹

Takeharu Kageyama ¹

Ivana Jevtovikj ¹

Piyal Ariyananda ¹

Alvaro Gordillo ^{1, 2}

Stephan A. Schunk ²

Frank Rominger ³

Peter Hofmann ^{1, 3}

Michael Limbach ^{1, 4}

Hide authors affiliations Show authors affiliations: 4 affiliations

CaRLa (Catalysis Research Laboratory), Im Neuenheimer Feld 584, 69120 Heidelberg, Germany |

hte Aktiengesellschaft, Kurpfalzring 104, 69123 Heidelberg, Germany |

Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany |

⁴

BASF SE, Carl-Bosch-Strasse 38, 67056 Ludwigshafen, Germany |

Publication type: Journal Article

Publication date: 2015-06-03

Royal Society of Chemistry (RSC)

Chemical Communications

scimago Q1

wos Q2

SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/c5cc01932j

Copy DOI

PubMed ID: 26060842

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.

Found

1 citation

Naranov Evgeny

🥼 🤝

PhD in Chemistry

53 publications, 656 citations, 14 reviews

h-index: 14

Lomonosov Moscow State University

A.V. Topchiev Institute of Petrochemical Synthesis RAS

1 citation

Soldatov Alexander

600 publications, 11 181 citations

h-index: 52

Southern Federal University

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GOST |

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Stieber S. C. E. et al. Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight // Chemical Communications. 2015. Vol. 51. No. 54. pp. 10907-10909.

GOST all authors (up to 50) Copy

Stieber S. C. E., Huguet N., Kageyama T., Jevtovikj I., Ariyananda P., Gordillo A., Schunk S. A., Rominger F., Hofmann P., Limbach M. Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight // Chemical Communications. 2015. Vol. 51. No. 54. pp. 10907-10909.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1039/c5cc01932j

UR - https://doi.org/10.1039/c5cc01932j

TI - Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

T2 - Chemical Communications

AU - Stieber, S Chantal E

AU - Huguet, Núria

AU - Kageyama, Takeharu

AU - Jevtovikj, Ivana

AU - Ariyananda, Piyal

AU - Gordillo, Alvaro

AU - Schunk, Stephan A.

AU - Rominger, Frank

AU - Hofmann, Peter

AU - Limbach, Michael

PY - 2015

DA - 2015/06/03

PB - Royal Society of Chemistry (RSC)

SP - 10907-10909

IS - 54

VL - 51

PMID - 26060842

SN - 1359-7345

SN - 1364-548X

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2015_Stieber,

author = {S Chantal E Stieber and Núria Huguet and Takeharu Kageyama and Ivana Jevtovikj and Piyal Ariyananda and Alvaro Gordillo and Stephan A. Schunk and Frank Rominger and Peter Hofmann and Michael Limbach},

title = {Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight},

journal = {Chemical Communications},

year = {2015},

volume = {51},

publisher = {Royal Society of Chemistry (RSC)},

month = {jun},

url = {https://doi.org/10.1039/c5cc01932j},

number = {54},

pages = {10907--10909},

doi = {10.1039/c5cc01932j}

}

MLA

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MLA Copy

Stieber, S. Chantal E., et al. “Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight.” Chemical Communications, vol. 51, no. 54, Jun. 2015, pp. 10907-10909. https://doi.org/10.1039/c5cc01932j.

Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

scimago Q1

wos Q2

SJR

1.037

CiteScore

7.4

Impact factor

4.2

ISSN

13597345 (Print)

1364548X (Electronic)