A highly reducing metal-free photoredox catalyst: design and application in radical dehalogenations
Emre H Discekici
1
,
Nicolas J Treat
2
,
Saemi O Poelma
1
,
Kaila M Mattson
1
,
Zachary M. Hudson
2
,
Yingdong Luo
1
,
C. J. Hawker
1, 2
,
Publication type: Journal Article
Publication date: 2015-06-18
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
26104847
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
Here we report the use of 10-phenylphenothiazine (PTH) as an inexpensive, highly reducing metal-free photocatalyst for the reduction of carbon-halogen bonds via the trapping of carbon-centered radical intermediates with a mild hydrogen atom donor. Dehalogenations were carried out on various substrates with excellent yields at room temperature in the presence of air.
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Metrics
287
Total citations:
287
Citations from 2024:
53
(18.53%)
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MLA
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GOST
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Discekici E. H. et al. A highly reducing metal-free photoredox catalyst: design and application in radical dehalogenations // Chemical Communications. 2015. Vol. 51. No. 58. pp. 11705-11708.
GOST all authors (up to 50)
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Discekici E. H., Treat N. J., Poelma S. O., Mattson K. M., Hudson Z. M., Luo Y., Hawker C. J., Read De Alaniz J. A highly reducing metal-free photoredox catalyst: design and application in radical dehalogenations // Chemical Communications. 2015. Vol. 51. No. 58. pp. 11705-11708.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c5cc04677g
UR - https://doi.org/10.1039/c5cc04677g
TI - A highly reducing metal-free photoredox catalyst: design and application in radical dehalogenations
T2 - Chemical Communications
AU - Discekici, Emre H
AU - Treat, Nicolas J
AU - Poelma, Saemi O
AU - Mattson, Kaila M
AU - Hudson, Zachary M.
AU - Luo, Yingdong
AU - Hawker, C. J.
AU - Read De Alaniz, J
PY - 2015
DA - 2015/06/18
PB - Royal Society of Chemistry (RSC)
SP - 11705-11708
IS - 58
VL - 51
PMID - 26104847
SN - 1359-7345
SN - 1364-548X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Discekici,
author = {Emre H Discekici and Nicolas J Treat and Saemi O Poelma and Kaila M Mattson and Zachary M. Hudson and Yingdong Luo and C. J. Hawker and J Read De Alaniz},
title = {A highly reducing metal-free photoredox catalyst: design and application in radical dehalogenations},
journal = {Chemical Communications},
year = {2015},
volume = {51},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://doi.org/10.1039/c5cc04677g},
number = {58},
pages = {11705--11708},
doi = {10.1039/c5cc04677g}
}
Cite this
MLA
Copy
Discekici, Emre H., et al. “A highly reducing metal-free photoredox catalyst: design and application in radical dehalogenations.” Chemical Communications, vol. 51, no. 58, Jun. 2015, pp. 11705-11708. https://doi.org/10.1039/c5cc04677g.
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