Energy and Environmental Science, volume 9, issue 3, pages 948-954
Glass-amorphous alkali-ion solid electrolytes and their performance in symmetrical cells
3
Energy and Geology National Laboratory (LNEG), R. da Amieira, 4466-901 S. Mamede de Infesta, Portugal
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Publication type: Journal Article
Publication date: 2016-01-01
Journal:
Energy and Environmental Science
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 32.5
ISSN: 17545692, 17545706
Environmental Chemistry
Pollution
Nuclear Energy and Engineering
Renewable Energy, Sustainability and the Environment
Abstract
Precursors of the crystalline antiperovskites A3−xHxOCl (A = Li or Na and 0 < x < 1) can be rendered glass/amorphous solid Li+ or Na+ electrolytes by the addition of water to its solvation limit with/without the addition of a small amount of an oxide or hydroxide. The solvated water is evaporated as HCl and 2(OH)− = O2− + H2O. The O2− attracts a Li+ or Na+ to form dipoles; the remaining Li+ or Na+ are mobile. The Li+ or Na+ ionic conductivities of the glass/amorphous solids have activation energies ΔHm < 0.1 eV and a room-temperature conductivity comparable to that of the best organic liquid electrolytes. Measurements of the dielectric loss tangent versus frequency show two overlapping resonances at room temperature with the Ba-doped Li-glass; they are nearly overlapping at temperatures 41 °C < T < 141 °C in the Ba-doped Na-glass. Galvanostatic charging of a symmetric Cu/Na-glass/Cu cell for 1 h showed a remarkable self-charge on switching to open circuit; charging for 15 h followed by discharging at an applied −0.1 mA of the symmetric cell showed, in the discharge mode, a replating of sodium on the anode at a positive cell current of +0.07 mA for over 15 h. A model for these behaviors is proposed. A symmetric Li/Li-glass/Li cell was cycled to demonstrate plating of Li on a current collector from the Li-glass electrolyte.
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Citations by publishers
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15
20
25
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IOP Publishing
1 publication, 0.93%
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Chinese Physical Society
1 publication, 0.93%
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Proceedings of the National Academy of Sciences (PNAS)
1 publication, 0.93%
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IEEE
1 publication, 0.93%
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The Electrochemical Society of Japan
1 publication, 0.93%
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Taylor & Francis
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1 publication, 0.93%
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1 publication, 0.93%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Braga M. H. et al. Glass-amorphous alkali-ion solid electrolytes and their performance in symmetrical cells // Energy and Environmental Science. 2016. Vol. 9. No. 3. pp. 948-954.
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Braga M. H., Murchison A. J., Ferreira J. A., Singh P., Goodenough J. Glass-amorphous alkali-ion solid electrolytes and their performance in symmetrical cells // Energy and Environmental Science. 2016. Vol. 9. No. 3. pp. 948-954.
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TY - JOUR
DO - 10.1039/C5EE02924D
UR - https://doi.org/10.1039/C5EE02924D
TI - Glass-amorphous alkali-ion solid electrolytes and their performance in symmetrical cells
T2 - Energy and Environmental Science
AU - Braga, M. Helena
AU - Ferreira, Jorge A.
AU - Murchison, Andrew J.
AU - Singh, Preetam
AU - Goodenough, John
PY - 2016
DA - 2016/01/01 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 948-954
IS - 3
VL - 9
SN - 1754-5692
SN - 1754-5706
ER -
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@article{2016_Braga,
author = {M. Helena Braga and Jorge A. Ferreira and Andrew J. Murchison and Preetam Singh and John Goodenough},
title = {Glass-amorphous alkali-ion solid electrolytes and their performance in symmetrical cells},
journal = {Energy and Environmental Science},
year = {2016},
volume = {9},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/C5EE02924D},
number = {3},
pages = {948--954},
doi = {10.1039/C5EE02924D}
}
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Braga, M. Helena, et al. “Glass-amorphous alkali-ion solid electrolytes and their performance in symmetrical cells.” Energy and Environmental Science, vol. 9, no. 3, Jan. 2016, pp. 948-954. https://doi.org/10.1039/C5EE02924D.
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