Catalysis Science and Technology, volume 6, issue 21, pages 7708-7717

Depolymerization of 1,4-polybutadiene by metathesis: high yield of large macrocyclic oligo(butadiene)s by ligand selectivity control

Publication type: Journal Article
Publication date: 2016-06-20
scimago Q2
wos Q2
SJR: 1.050
CiteScore: 8.7
Impact factor: 4.4
ISSN: 20444753, 20444761
Catalysis
Abstract

Herein, we demonstrate a practical high yield preparation of large macrocyclic oligo(butadiene)s, preferably the C16 to C44 fraction, from commercial 1,4-polybutadiene by exploring intramolecular backbiting using a series of commercially available Ru catalysts.

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