Catalysis Science and Technology, volume 8, issue 6, pages 1652-1662
BN nanoparticle/Ag hybrids with enhanced catalytic activity: theory and experiments
Konopatsky Anton
1
,
Firestein Konstantin L
1, 2
,
Leybo Denis
1
,
Popov Zakhar
1
,
Larionov Konstantin V.
1, 3
,
Kovalskii A. M.
1
,
Matveev A.T.
1
,
Manakhov Anton
1
,
Sorokin Pavel B.
1, 3
,
Golberg Dmitri
2, 4
,
Publication type: Journal Article
Publication date: 2018-01-09
Journal:
Catalysis Science and Technology
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 5
ISSN: 20444753, 20444761
Catalysis
Abstract
Hexagonal boron nitride nanoparticles (BNNPs) with different amounts of boron oxide on their surfaces were used as catalyst carriers. BNNPs/Ag nanohybrids were produced via ultraviolet (UV) decomposition of AgNO3 in a mixture of polyethylene glycol and BNNPs. High temperature (1600 °C, 1.5 h) vacuum annealing of BNNPs promoted small size (5–10 nm) Ag nanoparticle (AgNPs) formation on BN surfaces with narrow size distribution, whereas using BNNPs in their as-produced state resulted in large AgNPs with various sizes. An increase in the B2O3 content on the BNNPs surfaces (up to a certain point) during BNNP pre-annealing in air led to larger amounts of AgNPs on their surfaces. Experimental results were confirmed by theoretical calculations of the adhesion energy of the (111)Ag with (0001)h-BN and (100)B2O3 surfaces. In contrast to the nonwettability of the h-BN surface by AgNPs, silver bound well to B2O3 with the formation of a covalent bond at the interface. Excessive fraction of B2O3, however, was not beneficial in terms of obtaining the optimal contents of AgNPs. Results of catalytic activity tests demonstrated that BNNPs/Ag nanohybrids synthesized using BNNPs with an optimized amount of B2O3 possess significantly enhanced catalytic activity compared to BNNPs without or with excess amounts of oxide. Finally, the catalytic activity of nanohybrids was theoretically analyzed using density functional theory (DFT) calculations.
Citations by journals
|
1
2
|
|
|
ACS applied materials & interfaces
|
ACS applied materials & interfaces
2 publications, 9.52%
|
|
ACS Applied Nano Materials
|
ACS Applied Nano Materials
2 publications, 9.52%
|
|
Journal of Catalysis
|
Journal of Catalysis
2 publications, 9.52%
|
|
Catalysis Science and Technology
|
Catalysis Science and Technology
1 publication, 4.76%
|
|
Chemical Engineering Journal
|
Chemical Engineering Journal
1 publication, 4.76%
|
|
International Journal of Molecular Sciences
|
International Journal of Molecular Sciences
1 publication, 4.76%
|
|
Nanomaterials
|
Nanomaterials
1 publication, 4.76%
|
|
Molecules
|
Molecules
1 publication, 4.76%
|
|
Frontiers in Chemistry
|
Frontiers in Chemistry
1 publication, 4.76%
|
|
Materials Letters
|
Materials Letters
1 publication, 4.76%
|
|
Journal of Colloid and Interface Science
|
Journal of Colloid and Interface Science
1 publication, 4.76%
|
|
Applied Catalysis B: Environmental
|
Applied Catalysis B: Environmental
1 publication, 4.76%
|
|
ChemCatChem
|
ChemCatChem
1 publication, 4.76%
|
|
Physica E: Low-Dimensional Systems and Nanostructures
|
Physica E: Low-Dimensional Systems and Nanostructures
1 publication, 4.76%
|
|
Vacuum
|
Vacuum
1 publication, 4.76%
|
|
Journal of Physical Chemistry Letters
|
Journal of Physical Chemistry Letters
1 publication, 4.76%
|
|
Nanoscale
|
Nanoscale
1 publication, 4.76%
|
|
Journal of Functional Biomaterials
|
Journal of Functional Biomaterials
1 publication, 4.76%
|
|
1
2
|
Citations by publishers
|
1
2
3
4
5
6
7
8
|
|
|
Elsevier
|
Elsevier
8 publications, 38.1%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
5 publications, 23.81%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
4 publications, 19.05%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
2 publications, 9.52%
|
|
Frontiers Media S.A.
|
Frontiers Media S.A.
1 publication, 4.76%
|
|
Wiley
|
Wiley
1 publication, 4.76%
|
|
1
2
3
4
5
6
7
8
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023],"ids":[0,0,0,0,0,0],"codes":[0,0,0,0,0,0],"imageUrls":["","","","","",""],"datasets":[{"label":"Citations number","data":[2,5,3,4,4,3],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["9.52","23.81","14.29","19.05","19.05","14.29"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["ACS applied materials & interfaces","ACS Applied Nano Materials","Journal of Catalysis","Catalysis Science and Technology","Chemical Engineering Journal","International Journal of Molecular Sciences","Nanomaterials","Molecules","Frontiers in Chemistry","Materials Letters","Journal of Colloid and Interface Science","Applied Catalysis B: Environmental","ChemCatChem","Physica E: Low-Dimensional Systems and Nanostructures","Vacuum","Journal of Physical Chemistry Letters","Nanoscale","Journal of Functional Biomaterials"],"ids":[1458,1600,20883,2605,16275,14627,10051,1770,6407,548,24202,18270,10149,13603,11149,21963,228,19043],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp"],"datasets":[{"label":"","data":[2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[9.52,9.52,9.52,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","American Chemical Society (ACS)","Multidisciplinary Digital Publishing Institute (MDPI)","Royal Society of Chemistry (RSC)","Frontiers Media S.A.","Wiley"],"ids":[17,40,202,123,208,11],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[8,5,4,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[38.1,23.81,19.05,9.52,4.76,4.76],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Konopatsky A. et al. BN nanoparticle/Ag hybrids with enhanced catalytic activity: theory and experiments // Catalysis Science and Technology. 2018. Vol. 8. No. 6. pp. 1652-1662.
GOST all authors (up to 50)
Copy
Konopatsky A., Firestein K. L., Leybo D., Popov Z., Larionov K. V., Steinman A. E., Kovalskii A. M., Matveev A., Manakhov A., Sorokin P. B., Golberg D., Shtansky D. V. BN nanoparticle/Ag hybrids with enhanced catalytic activity: theory and experiments // Catalysis Science and Technology. 2018. Vol. 8. No. 6. pp. 1652-1662.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/C7CY02207G
UR - https://doi.org/10.1039%2FC7CY02207G
TI - BN nanoparticle/Ag hybrids with enhanced catalytic activity: theory and experiments
T2 - Catalysis Science and Technology
AU - Konopatsky, Anton
AU - Firestein, Konstantin L
AU - Popov, Zakhar
AU - Kovalskii, A. M.
AU - Matveev, A.T.
AU - Manakhov, Anton
AU - Sorokin, Pavel B.
AU - Golberg, Dmitri
AU - Shtansky, Dmitry V.
AU - Leybo, Denis
AU - Larionov, Konstantin V.
AU - Steinman, Alexander E
PY - 2018
DA - 2018/01/09 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 1652-1662
IS - 6
VL - 8
SN - 2044-4753
SN - 2044-4761
ER -
Cite this
BibTex
Copy
@article{2018_Konopatsky,
author = {Anton Konopatsky and Konstantin L Firestein and Zakhar Popov and A. M. Kovalskii and A.T. Matveev and Anton Manakhov and Pavel B. Sorokin and Dmitri Golberg and Dmitry V. Shtansky and Denis Leybo and Konstantin V. Larionov and Alexander E Steinman},
title = {BN nanoparticle/Ag hybrids with enhanced catalytic activity: theory and experiments},
journal = {Catalysis Science and Technology},
year = {2018},
volume = {8},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039%2FC7CY02207G},
number = {6},
pages = {1652--1662},
doi = {10.1039/C7CY02207G}
}
Cite this
MLA
Copy
Konopatsky, Anton, et al. “BN nanoparticle/Ag hybrids with enhanced catalytic activity: theory and experiments.” Catalysis Science and Technology, vol. 8, no. 6, Jan. 2018, pp. 1652-1662. https://doi.org/10.1039%2FC7CY02207G.