Mechanochemical Suzuki polycondensation – from linear to hyperbranched polyphenylenes
Тип публикации: Journal Article
Дата публикации: 2017-05-05
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.811
CiteScore: 16
Impact factor: 10.6
ISSN: 14639262, 14639270
Environmental Chemistry
Pollution
Краткое описание
The mechanochemical Suzuki polycondensation constitutes a sustainable alternative to classical solvent-based polymerization reactions for poly(phenylene)s. In order to establish a basic understanding of the process, important reaction parameters like the milling material, halide type and polymerization system are investigated. Under optimized conditions, we have been able to synthesize linear polymers with an outstanding degree of polymerization of 164, in a ligand free environment – in as little as 30 minutes. In addition, the developed principle is broadened to a hyperbranched system with high temperature resistance and high yields in short reaction times.
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Grätz S., Wolfrum B., Borchardt L. Mechanochemical Suzuki polycondensation – from linear to hyperbranched polyphenylenes // Green Chemistry. 2017. Vol. 19. No. 13. pp. 2973-2979.
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Grätz S., Wolfrum B., Borchardt L. Mechanochemical Suzuki polycondensation – from linear to hyperbranched polyphenylenes // Green Chemistry. 2017. Vol. 19. No. 13. pp. 2973-2979.
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TY - JOUR
DO - 10.1039/C7GC00693D
UR - https://doi.org/10.1039/C7GC00693D
TI - Mechanochemical Suzuki polycondensation – from linear to hyperbranched polyphenylenes
T2 - Green Chemistry
AU - Grätz, Sven
AU - Wolfrum, B
AU - Borchardt, Lars
PY - 2017
DA - 2017/05/05
PB - Royal Society of Chemistry (RSC)
SP - 2973-2979
IS - 13
VL - 19
SN - 1463-9262
SN - 1463-9270
ER -
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@article{2017_Grätz,
author = {Sven Grätz and B Wolfrum and Lars Borchardt},
title = {Mechanochemical Suzuki polycondensation – from linear to hyperbranched polyphenylenes},
journal = {Green Chemistry},
year = {2017},
volume = {19},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://doi.org/10.1039/C7GC00693D},
number = {13},
pages = {2973--2979},
doi = {10.1039/C7GC00693D}
}
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MLA
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Grätz, Sven, et al. “Mechanochemical Suzuki polycondensation – from linear to hyperbranched polyphenylenes.” Green Chemistry, vol. 19, no. 13, May. 2017, pp. 2973-2979. https://doi.org/10.1039/C7GC00693D.
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