Synthesis, X-ray structure and electrochemical properties of hybrid binuclear metallophthalocyaninate-capped tris-pyridineoximates
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Vernadskii Institute of General and Inorganic Chemistry of the National Academy of Sciences of Ukraine, 03680 Kiev, Ukraine
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Publication type: Journal Article
Publication date: 2017-03-10
scimago Q2
wos Q3
SJR: 0.493
CiteScore: 5.0
Impact factor: 2.5
ISSN: 11440546, 13699261
Materials Chemistry
General Chemistry
Catalysis
Abstract
New antimony-capped iron and nickel(II) tris-pyridineoximates with a labile triethylantimony cross-linking group were obtained by template condensation of 2-acetylpyridinoxime with triethylantimony(V) dibromide on the corresponding metal ion as a matrix. They easily undergo transmetallation (capping group exchange) with Lewis-acidic zirconium and hafnium(IV) phthalocyaninates (Pc) to give binuclear MPc-capped tris-pyridineoximates. The obtained hybrid complexes and their precursors were thoroughly characterized (among others, by single-crystal X-ray diffraction), and their redox properties were studied by cyclic and differential pulse voltammetry.
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Total citations:
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Dudkin S. V. et al. Synthesis, X-ray structure and electrochemical properties of hybrid binuclear metallophthalocyaninate-capped tris-pyridineoximates // New Journal of Chemistry. 2017. Vol. 41. No. 9. pp. 3251-3259.
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Dudkin S. V., Belov A. S., Nelyubina Y. V., Savchuk A. V., Pavlov A., Novikov V. V., Voloshin Y. Z. Synthesis, X-ray structure and electrochemical properties of hybrid binuclear metallophthalocyaninate-capped tris-pyridineoximates // New Journal of Chemistry. 2017. Vol. 41. No. 9. pp. 3251-3259.
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RIS
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TY - JOUR
DO - 10.1039/C7NJ00131B
UR - https://doi.org/10.1039/C7NJ00131B
TI - Synthesis, X-ray structure and electrochemical properties of hybrid binuclear metallophthalocyaninate-capped tris-pyridineoximates
T2 - New Journal of Chemistry
AU - Dudkin, Semyon V.
AU - Belov, Alexander S.
AU - Nelyubina, Yulia V.
AU - Savchuk, Anastasia V.
AU - Pavlov, Alexander
AU - Novikov, Valentin V
AU - Voloshin, Yan Z.
PY - 2017
DA - 2017/03/10
PB - Royal Society of Chemistry (RSC)
SP - 3251-3259
IS - 9
VL - 41
SN - 1144-0546
SN - 1369-9261
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Dudkin,
author = {Semyon V. Dudkin and Alexander S. Belov and Yulia V. Nelyubina and Anastasia V. Savchuk and Alexander Pavlov and Valentin V Novikov and Yan Z. Voloshin},
title = {Synthesis, X-ray structure and electrochemical properties of hybrid binuclear metallophthalocyaninate-capped tris-pyridineoximates},
journal = {New Journal of Chemistry},
year = {2017},
volume = {41},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://doi.org/10.1039/C7NJ00131B},
number = {9},
pages = {3251--3259},
doi = {10.1039/C7NJ00131B}
}
Cite this
MLA
Copy
Dudkin, Semyon V., et al. “Synthesis, X-ray structure and electrochemical properties of hybrid binuclear metallophthalocyaninate-capped tris-pyridineoximates.” New Journal of Chemistry, vol. 41, no. 9, Mar. 2017, pp. 3251-3259. https://doi.org/10.1039/C7NJ00131B.