Journal of Materials Chemistry A, volume 5, issue 34, pages 18111-18119
Lithium ion conductivity in Li2S–P2S5 glasses – building units and local structure evolution during the crystallization of superionic conductors Li3PS4, Li7P3S11 and Li4P2S7
Christian Dietrich
1
,
Dominik A. Weber
1
,
Sylvio Indris
3
,
Sean P Culver
1
,
Dirk Walter
4
,
Jürgen Janek
1, 2
,
Publication type: Journal Article
Publication date: 2017-08-01
Journal:
Journal of Materials Chemistry A
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 11.9
ISSN: 20507488, 20507496, 09599428, 13645501
General Chemistry
General Materials Science
Renewable Energy, Sustainability and the Environment
Abstract
Motivated by the high lithium ion conductivities of lithium thiophosphate glasses, a detailed study is performed on the local chemical nature of the thiophosphate building units within these materials. Using Raman and 31P MAS NMR (Magic Angle Spinning – Nuclear Magnetic Resonance) spectroscopy, the continuous change from dominant P2S74− (di-tetrahedral) anions to PS43− (mono-tetrahedral) anions with increasing Li2S fraction in the (Li2S)x(P2S5)(100−x) glasses is observed. In addition, synchrotron pair distribution function analysis (PDF) of synchrotron X-ray total scattering data is employed to monitor in situ crystallization and phase evolution in this class of materials. Depending on the composition, different crystalline phases evolve, which possess different decomposition temperatures into less conducting phases. The results highlight the critical influence of the local anionic building units on the cation mobility and thermal stability, with PS43− tetrahedra forming the most thermally robust glass ceramics with the highest ionic conductivity.
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Dietrich C. et al. Lithium ion conductivity in Li2S–P2S5 glasses – building units and local structure evolution during the crystallization of superionic conductors Li3PS4, Li7P3S11 and Li4P2S7 // Journal of Materials Chemistry A. 2017. Vol. 5. No. 34. pp. 18111-18119.
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Dietrich C., Weber D. A., Sedlmaier S. J., Indris S., Culver S. P., Walter D., Janek J., Zeier W. G. Lithium ion conductivity in Li2S–P2S5 glasses – building units and local structure evolution during the crystallization of superionic conductors Li3PS4, Li7P3S11 and Li4P2S7 // Journal of Materials Chemistry A. 2017. Vol. 5. No. 34. pp. 18111-18119.
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TY - JOUR
DO - 10.1039/C7TA06067J
UR - https://doi.org/10.1039/C7TA06067J
TI - Lithium ion conductivity in Li2S–P2S5 glasses – building units and local structure evolution during the crystallization of superionic conductors Li3PS4, Li7P3S11 and Li4P2S7
T2 - Journal of Materials Chemistry A
AU - Dietrich, Christian
AU - Walter, Dirk
AU - Janek, Jürgen
AU - Zeier, Wolfgang G.
AU - Weber, Dominik A.
AU - Sedlmaier, Stefan J.
AU - Indris, Sylvio
AU - Culver, Sean P
PY - 2017
DA - 2017/08/01 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 18111-18119
IS - 34
VL - 5
SN - 2050-7488
SN - 2050-7496
SN - 0959-9428
SN - 1364-5501
ER -
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@article{2017_Dietrich,
author = {Christian Dietrich and Dirk Walter and Jürgen Janek and Wolfgang G. Zeier and Dominik A. Weber and Stefan J. Sedlmaier and Sylvio Indris and Sean P Culver},
title = {Lithium ion conductivity in Li2S–P2S5 glasses – building units and local structure evolution during the crystallization of superionic conductors Li3PS4, Li7P3S11 and Li4P2S7},
journal = {Journal of Materials Chemistry A},
year = {2017},
volume = {5},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://doi.org/10.1039/C7TA06067J},
number = {34},
pages = {18111--18119},
doi = {10.1039/C7TA06067J}
}
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Dietrich, Christian, et al. “Lithium ion conductivity in Li2S–P2S5 glasses – building units and local structure evolution during the crystallization of superionic conductors Li3PS4, Li7P3S11 and Li4P2S7.” Journal of Materials Chemistry A, vol. 5, no. 34, Aug. 2017, pp. 18111-18119. https://doi.org/10.1039/C7TA06067J.