Journal of Materials Chemistry A, volume 6, issue 2, pages 645-651
Effect of Si substitution on the structural and transport properties of superionic Li-argyrodites
Nicoló Minafra
1, 2
,
Nicolò Minafra
1, 2
,
Sean P Culver
1
,
Thorben Krauskopf
1
,
Anatoliy Senyshyn
3
,
Wolfgang G. Zeier
1, 4
2
Publication type: Journal Article
Publication date: 2018-01-01
Journal:
Journal of Materials Chemistry A
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 11.9
ISSN: 20507488, 20507496, 09599428, 13645501
General Chemistry
General Materials Science
Renewable Energy, Sustainability and the Environment
Abstract
Inspired by the recent interest in lithium ion conducting argyrodites as solid electrolytes for solid-state batteries, we have investigated the influence of aliovalent substitution in Li6PS5Br. Using Rietveld refinements against X-ray and neutron diffraction, coupled with impedance spectroscopy, we monitor the influence of Si4+ substitution for P5+ in Li6+xP1−xSixS5Br on the structure and ionic transport properties. A step-wise incorporation of Si4+ leads to an expansion of the unit cell, as well as the inclusion of additional Li+ within the structure. The increasing Li content occupies the structural transition state and, in combination with the structural changes, leads to a three-fold improvement of the ionic conductivity. This work demonstrates that the argyrodite material class can be optimized through aliovalent substitution, thereby making argyrodites an ideal system for studying solid electrolytes within the field of solid-state batteries.
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Minafra N. et al. Effect of Si substitution on the structural and transport properties of superionic Li-argyrodites // Journal of Materials Chemistry A. 2018. Vol. 6. No. 2. pp. 645-651.
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Minafra N., Minafra N., Culver S. P., Krauskopf T., Senyshyn A., Zeier W. G. Effect of Si substitution on the structural and transport properties of superionic Li-argyrodites // Journal of Materials Chemistry A. 2018. Vol. 6. No. 2. pp. 645-651.
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TY - JOUR
DO - 10.1039/C7TA08581H
UR - https://doi.org/10.1039/C7TA08581H
TI - Effect of Si substitution on the structural and transport properties of superionic Li-argyrodites
T2 - Journal of Materials Chemistry A
AU - Minafra, Nicoló
AU - Culver, Sean P
AU - Krauskopf, Thorben
AU - Senyshyn, Anatoliy
AU - Zeier, Wolfgang G.
AU - Minafra, Nicolò
PY - 2018
DA - 2018/01/01 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 645-651
IS - 2
VL - 6
SN - 2050-7488
SN - 2050-7496
SN - 0959-9428
SN - 1364-5501
ER -
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@article{2018_Minafra,
author = {Nicoló Minafra and Sean P Culver and Thorben Krauskopf and Anatoliy Senyshyn and Wolfgang G. Zeier and Nicolò Minafra},
title = {Effect of Si substitution on the structural and transport properties of superionic Li-argyrodites},
journal = {Journal of Materials Chemistry A},
year = {2018},
volume = {6},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/C7TA08581H},
number = {2},
pages = {645--651},
doi = {10.1039/C7TA08581H}
}
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Minafra, Nicoló, et al. “Effect of Si substitution on the structural and transport properties of superionic Li-argyrodites.” Journal of Materials Chemistry A, vol. 6, no. 2, Jan. 2018, pp. 645-651. https://doi.org/10.1039/C7TA08581H.
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