Chemical Communications

, volume 55 , issue 3 , pages 290-293

Interaction of a trinuclear copper(i) pyrazolate with alkynes and carbon–carbon triple bond activation

Aleksei A Titov ^{1, 2, 3, 4}

Vladimir A Larionov ^{1, 2, 3, 4, 5, 6, 7}

Alexander F. Smol’yakov ^{1, 2, 3, 4}

Maria I Godovikova ^{1, 2, 3, 4}

Ekaterina Titova ^{1, 5}

Ekaterina M Titova ^{2, 3, 4, 6, 7}

Viktor Maleev ^{1, 2, 3, 4}

Elena S. Shubina ^{1, 2, 3, 4}

Hide authors affiliations Show authors affiliations: 7 affiliations

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS), Vavilov St. 28, 119991 Moscow, Russian Federation |

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS) |

119991 Moscow

⁴

RUSSIAN FEDERATION |

⁵

Peoples’ Friendship University of Russia (RUDN University), Miklukho-Maklaya St. 6, 117198 Moscow, Russian Federation |

⁶

Peoples’ Friendship University of Russia (RUDN University) |

⁷

117198 Moscow

Publication type: Journal Article

Publication date: 2019-01-01

Royal Society of Chemistry (RSC)

Chemical Communications

scimago Q1

wos Q2

SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/C8CC08592G

Copy DOI

PubMed ID: 30411109

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

The trinuclear copper(i) pyrazolate {[3,5-(CF3)2Pz]Cu}3 forms η2-copper/alkyne triple bond coordinated structures in the presence of acetylenes. There is no coordination of copper atoms to the phenyl ring of phenylacetylene and copper(i) acetylide formation during the interaction. It was observed that the complexes formed are the active catalytic species in click reactions.

Found

8 citations

Filippov Oleg

🥼

DSc in Chemistry

137 publications, 2 409 citations, 45 reviews

h-index: 26

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

8 citations

Shubina Elena

DSc in Chemistry, professor

264 publications, 5 882 citations, 16 reviews

h-index: 38

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Molecular spectroscopy

1 citation

Dorovatovskii Pavel

340 publications, 4 036 citations

h-index: 28

National Research Centre "Kurchatov Institute"

1 citation

Novikov Alexander

🥼 🤝

PhD in Chemistry

414 publications, 8 170 citations, 251 reviews

h-index: 54

Saint Petersburg State University

Lomonosov Moscow State University

National Research University Higher School of Economics

ITMO University

Research interests

Computational chemistry

Machine learning

Non-covalent Interactions

Quantum Chemistry

Reaction mechanisms

Supramolecular chemistry

1 citation

Shakirova Julia

55 publications, 900 citations

h-index: 18

Saint Petersburg State University

1 citation

Adonin Sergey

DSc in Chemistry, professor

200 publications, 3 004 citations, 21 reviews

h-index: 30

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

South Ural State University

1 citation

Larionov Vladimir

🥼 🤝

DSc in Chemistry

54 publications, 1 085 citations, 106 reviews

h-index: 18

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Peoples' Friendship University of Russia

Research interests

Asymmetric catalysis

1 citation

Baigildin Vadim

🤝

PhD in Chemistry, senior lecturer

28 publications, 263 citations

h-index: 10

Saint Petersburg State University

Research interests

Photophysics and photochemistry of polyatomic systems and nanoparticles

Physical chemistry of polymers

Polymer Chemistry

Synthesis of polymers

1 citation

Sakhapov Ilyas

🥼 🤝

PhD in Chemistry

44 publications, 355 citations

h-index: 12

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Electrochemistry

Green chemistry

1 citation

Medvedev Michael

PhD in Physics and Mathematics, associate professor

85 publications, 2 074 citations, 7 reviews

h-index: 19

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

1 citation

Mikhaylov Vladimir

PhD in Chemistry

20 publications, 381 citations

h-index: 11

Saint Petersburg State University

Research interests

Catalysis

1 citation

Bondarenko Mikhail

🤝

PhD in Chemistry

33 publications, 389 citations

h-index: 10

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

South Ural State University

Research interests

Coordination Chemistry

Halogen connection

Metal-organic coordination polymers

Supramolecular chemistry

1 citation

Sorokoumov Viktor

PhD in Chemistry

58 publications, 783 citations

h-index: 15

Saint Petersburg State University

I. M. Sechenov Institute of Evolutionary Physiology and Biochemistry of the Russian Academy of Sciences

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Cite this

GOST |

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GOST Copy

Titov A. A. et al. Interaction of a trinuclear copper(i) pyrazolate with alkynes and carbon–carbon triple bond activation // Chemical Communications. 2019. Vol. 55. No. 3. pp. 290-293.

GOST all authors (up to 50) Copy

Titov A. A., Larionov V. A., Smol’yakov A. F., Godovikova M. I., Titova E., Titova E. M., Maleev V., Shubina E. S. Interaction of a trinuclear copper(i) pyrazolate with alkynes and carbon–carbon triple bond activation // Chemical Communications. 2019. Vol. 55. No. 3. pp. 290-293.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1039/C8CC08592G

UR - https://xlink.rsc.org/?DOI=C8CC08592G

TI - Interaction of a trinuclear copper(i) pyrazolate with alkynes and carbon–carbon triple bond activation

T2 - Chemical Communications

AU - Titov, Aleksei A

AU - Larionov, Vladimir A

AU - Smol’yakov, Alexander F.

AU - Godovikova, Maria I

AU - Titova, Ekaterina

AU - Titova, Ekaterina M

AU - Maleev, Viktor

AU - Shubina, Elena S.

PY - 2019

DA - 2019/01/01

PB - Royal Society of Chemistry (RSC)

SP - 290-293

IS - 3

VL - 55

PMID - 30411109

SN - 1359-7345

SN - 1364-548X

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Titov,

author = {Aleksei A Titov and Vladimir A Larionov and Alexander F. Smol’yakov and Maria I Godovikova and Ekaterina Titova and Ekaterina M Titova and Viktor Maleev and Elena S. Shubina},

title = {Interaction of a trinuclear copper(i) pyrazolate with alkynes and carbon–carbon triple bond activation},

journal = {Chemical Communications},

year = {2019},

volume = {55},

publisher = {Royal Society of Chemistry (RSC)},

month = {jan},

url = {https://xlink.rsc.org/?DOI=C8CC08592G},

number = {3},

pages = {290--293},

doi = {10.1039/C8CC08592G}

}

MLA

Cite this

MLA Copy

Titov, Aleksei A., et al. “Interaction of a trinuclear copper(i) pyrazolate with alkynes and carbon–carbon triple bond activation.” Chemical Communications, vol. 55, no. 3, Jan. 2019, pp. 290-293. https://xlink.rsc.org/?DOI=C8CC08592G.

Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

scimago Q1

wos Q2

SJR

1.037

CiteScore

7.4

Impact factor

4.2

ISSN

13597345 (Print)

1364548X (Electronic)

Labs

Laboratory of Metal Hydrides

Profiles