Halogenated triarylboranes: synthesis, properties and applications in catalysis
2
Cardiff Catalysis Institute
|
3
School of chemistry
5
CARDIFF
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6
UK
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Publication type: Journal Article
Publication date: 2020-02-26
scimago Q1
wos Q1
SJR: 11.467
CiteScore: 73.2
Impact factor: 39.0
ISSN: 03060012, 14604744
PubMed ID:
32100762
General Chemistry
Abstract
Halogenated triarylboranes (BAr3) have been known for decades, however it has only been since the surge of interest in main group catalysis that their application as strong Lewis acid catalysts has been recognised. This review aims to look past the popular tris(pentafluorophenyl)borane [B(C6F5)3] to the other halogenated triarylboranes, to give a greater breadth of understanding as to how tuning the Lewis acidity of BAr3 by modifications of the aryl rings can lead to improved reactivity. In this review, a discussion on Lewis acidity determination of boranes is given, the synthesis of these boranes is discussed, and examples of how they are being used for catalysis and frustrated Lewis pair (FLP) chemistry are explained.
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Metrics
171
Total citations:
171
Citations from 2025:
33
(19.3%)
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GOST
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Carden J. L. et al. Halogenated triarylboranes: synthesis, properties and applications in catalysis // Chemical Society Reviews. 2020. Vol. 49. No. 6. pp. 1706-1725.
GOST all authors (up to 50)
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Carden J. L., Dasgupta A., Melen R. L. Halogenated triarylboranes: synthesis, properties and applications in catalysis // Chemical Society Reviews. 2020. Vol. 49. No. 6. pp. 1706-1725.
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RIS
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TY - JOUR
DO - 10.1039/C9CS00769E
UR - https://xlink.rsc.org/?DOI=C9CS00769E
TI - Halogenated triarylboranes: synthesis, properties and applications in catalysis
T2 - Chemical Society Reviews
AU - Carden, Jamie L
AU - Dasgupta, Ayan
AU - Melen, Rebecca L.
PY - 2020
DA - 2020/02/26
PB - Royal Society of Chemistry (RSC)
SP - 1706-1725
IS - 6
VL - 49
PMID - 32100762
SN - 0306-0012
SN - 1460-4744
ER -
Cite this
BibTex (up to 50 authors)
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@article{2020_Carden,
author = {Jamie L Carden and Ayan Dasgupta and Rebecca L. Melen},
title = {Halogenated triarylboranes: synthesis, properties and applications in catalysis},
journal = {Chemical Society Reviews},
year = {2020},
volume = {49},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://xlink.rsc.org/?DOI=C9CS00769E},
number = {6},
pages = {1706--1725},
doi = {10.1039/C9CS00769E}
}
Cite this
MLA
Copy
Carden, Jamie L., et al. “Halogenated triarylboranes: synthesis, properties and applications in catalysis.” Chemical Society Reviews, vol. 49, no. 6, Feb. 2020, pp. 1706-1725. https://xlink.rsc.org/?DOI=C9CS00769E.