Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system
Тип публикации: Journal Article
Дата публикации: 2019-05-03
scimago Q1
wos Q2
БС1
SJR: 0.842
CiteScore: 7.6
Impact factor: 3.9
ISSN: 17599954, 17599962
Organic Chemistry
Biochemistry
Polymers and Plastics
Bioengineering
Краткое описание
Amphiphilic triblock terpolymers have attractive applications in the preparation of nanoparticles with controlled morphology. An additional level of morphology control can be provided by reactive blocks, whose interactions with the solvent vary under different stimuli. In this work, we synthesized a triblock terpolymer (poly(acrylic acid)-b-poly(4-hydroxystyrene)-b-poly{1-[4-(1-methyl-1,2-dicarba-closo-dodecaborane-2-yl methyl)-phenyl]ethylene}) (PAA-b-PHS-b-PSC) containing carboranes as pendant groups by reversible addition fragmentation chain transfer (RAFT) polymerization and subsequently studied its behavior in aqueous solution. Once the nanoparticles were formed, the solubility of the second and third blocks was changed via pH and CsF reactions, respectively. The resulting micelles work as an ON/OFF system, using changes in fluorescence intensity at different pH values.
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Fernandez Alvarez R. et al. Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system // Polymer Chemistry. 2019. Vol. 10. No. 22. pp. 2774-2780.
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Fernandez Alvarez R., Hlavatovičová E., Rodzeń K., Strachota A., Kereïche S., Matějíček P., Cabrera González J., Sillanpää R., Uchman M. Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system // Polymer Chemistry. 2019. Vol. 10. No. 22. pp. 2774-2780.
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TY - JOUR
DO - 10.1039/c9py00518h
UR - https://xlink.rsc.org/?DOI=C9PY00518H
TI - Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system
T2 - Polymer Chemistry
AU - Fernandez Alvarez, Roberto
AU - Hlavatovičová, Eva
AU - Rodzeń, Krzysztof
AU - Strachota, Adam
AU - Kereïche, Sami
AU - Matějíček, Pavel
AU - Cabrera González, Justo
AU - Sillanpää, Reijo
AU - Uchman, Mariusz
PY - 2019
DA - 2019/05/03
PB - Royal Society of Chemistry (RSC)
SP - 2774-2780
IS - 22
VL - 10
SN - 1759-9954
SN - 1759-9962
ER -
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@article{2019_Fernandez Alvarez,
author = {Roberto Fernandez Alvarez and Eva Hlavatovičová and Krzysztof Rodzeń and Adam Strachota and Sami Kereïche and Pavel Matějíček and Justo Cabrera González and Reijo Sillanpää and Mariusz Uchman},
title = {Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system},
journal = {Polymer Chemistry},
year = {2019},
volume = {10},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://xlink.rsc.org/?DOI=C9PY00518H},
number = {22},
pages = {2774--2780},
doi = {10.1039/c9py00518h}
}
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MLA
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Fernandez Alvarez, Roberto, et al. “Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system.” Polymer Chemistry, vol. 10, no. 22, May. 2019, pp. 2774-2780. https://xlink.rsc.org/?DOI=C9PY00518H.