The effect of terminal N-donor aromatic ligands on the sensitization and emission of lanthanide ions in Zn2Ln (Ln = Eu, Tb) complexes with 4-biphenylcarboxylate anions
Stanislav N Melnikov
1, 2, 3, 4
,
Igor S Evstifeev
1, 2, 3, 4
,
Stanislav Alexandrovich Nikolaevskii
1, 2, 3, 4
,
Ivan V Ananyev
4, 5, 6, 7
,
Evgenia A. Varaksina
3, 4, 5, 6, 7, 8, 9
,
Ilya V. Taydakov
3, 4, 5, 6, 7, 8, 9
,
Alexander S. Goloveshkin
4, 5, 6, 7
,
Aleksey A Sidorov
1, 2, 3, 4
,
Mikhail A. Kiskin
1, 2, 3, 4
,
Igor L. Eremenko
1, 2, 3, 4
3
119991 Moscow
4
RUSSIAN FEDERATION
|
7
Moscow
Publication type: Journal Article
Publication date: 2021-06-17
scimago Q2
wos Q3
SJR: 0.493
CiteScore: 5.0
Impact factor: 2.5
ISSN: 11440546, 13699261
Materials Chemistry
General Chemistry
Catalysis
Abstract
The systematic series of Zn–Ln trinuclear carboxylate molecular complexes of general formula [Zn2Ln(NO3)(phbz)6(L)2] (Ln = Eu, Gd, and Tb, where phbz is the anion of 4-biphenylcarboxylic acid, and L is pyridine, 2,3-lutidine or 2,2′-bipyridine) were synthesized. It was found that [Zn2Eu(NO3)(phbz)6(py)2] can be obtained in two phases, crystallized in the triclinic P and monoclinic P21/n space groups, and solvated acetonitrile molecules are able to prevent the formation of intermolecular π–π stacking interactions between the aromatic fragments of [Zn2Eu(NO3)(phbz)6(py)2]. Heterometallic Zn2Eu and Zn2Tb compounds possess bright metal-centered luminescence with quantum yields up to 62%. The influence of an N-donor ligand type on the efficiency of luminescence sensitization was studied.
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17
Total citations:
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Citations from 2024:
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Melnikov S. N. et al. The effect of terminal N-donor aromatic ligands on the sensitization and emission of lanthanide ions in Zn2Ln (Ln = Eu, Tb) complexes with 4-biphenylcarboxylate anions // New Journal of Chemistry. 2021. Vol. 45. No. 30. pp. 13349-13359.
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Melnikov S. N., Evstifeev I. S., Nikolaevskii S. A., Ananyev I. V., Varaksina E. A., Taydakov I. V., Goloveshkin A. S., Sidorov A. A., Kiskin M. A., Eremenko I. L. The effect of terminal N-donor aromatic ligands on the sensitization and emission of lanthanide ions in Zn2Ln (Ln = Eu, Tb) complexes with 4-biphenylcarboxylate anions // New Journal of Chemistry. 2021. Vol. 45. No. 30. pp. 13349-13359.
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TY - JOUR
DO - 10.1039/D0NJ05994C
UR - https://xlink.rsc.org/?DOI=D0NJ05994C
TI - The effect of terminal N-donor aromatic ligands on the sensitization and emission of lanthanide ions in Zn2Ln (Ln = Eu, Tb) complexes with 4-biphenylcarboxylate anions
T2 - New Journal of Chemistry
AU - Melnikov, Stanislav N
AU - Evstifeev, Igor S
AU - Nikolaevskii, Stanislav Alexandrovich
AU - Ananyev, Ivan V
AU - Varaksina, Evgenia A.
AU - Taydakov, Ilya V.
AU - Goloveshkin, Alexander S.
AU - Sidorov, Aleksey A
AU - Kiskin, Mikhail A.
AU - Eremenko, Igor L.
PY - 2021
DA - 2021/06/17
PB - Royal Society of Chemistry (RSC)
SP - 13349-13359
IS - 30
VL - 45
SN - 1144-0546
SN - 1369-9261
ER -
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BibTex (up to 50 authors)
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@article{2021_Melnikov,
author = {Stanislav N Melnikov and Igor S Evstifeev and Stanislav Alexandrovich Nikolaevskii and Ivan V Ananyev and Evgenia A. Varaksina and Ilya V. Taydakov and Alexander S. Goloveshkin and Aleksey A Sidorov and Mikhail A. Kiskin and Igor L. Eremenko},
title = {The effect of terminal N-donor aromatic ligands on the sensitization and emission of lanthanide ions in Zn2Ln (Ln = Eu, Tb) complexes with 4-biphenylcarboxylate anions},
journal = {New Journal of Chemistry},
year = {2021},
volume = {45},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://xlink.rsc.org/?DOI=D0NJ05994C},
number = {30},
pages = {13349--13359},
doi = {10.1039/D0NJ05994C}
}
Cite this
MLA
Copy
Melnikov, Stanislav N., et al. “The effect of terminal N-donor aromatic ligands on the sensitization and emission of lanthanide ions in Zn2Ln (Ln = Eu, Tb) complexes with 4-biphenylcarboxylate anions.” New Journal of Chemistry, vol. 45, no. 30, Jun. 2021, pp. 13349-13359. https://xlink.rsc.org/?DOI=D0NJ05994C.