Diastereodivergent synthesis of dispiroheterocyclic structures comprising pyrrolidinyloxindole and imidazothiazolotriazine moieties
Тип публикации: Journal Article
Дата публикации: 2020-08-24
scimago Q2
wos Q2
БС1
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
32856678
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
Highly diastereoselective methods for the synthesis of two different diastereomers of polynuclear dispiroheterocyclic compounds with five chiral centers comprising pyrrolidinyloxindole and imidazothiazolotriazine moieties (dispiro[imidazo[4,5-e]thiazolo[2,3-c]-1,2,4-triazine-7,3'-pyrrolidine-2',3''-indoles]) have been developed on the basis of a dipolar cycloaddition of azomethine ylides to benzylidene derivatives of imidazothiazolotriazines and an alkali-induced rearrangement of the thiazolotriazine fragment. The different sequence of the cycloaddition and rearrangement stages allows us to perform the targeted synthesis of two diastereomerically pure products from the same starting compounds.
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Izmestev A. N. et al. Diastereodivergent synthesis of dispiroheterocyclic structures comprising pyrrolidinyloxindole and imidazothiazolotriazine moieties // Organic and Biomolecular Chemistry. 2020. Vol. 18. No. 35. pp. 6905-6911.
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Izmestev A. N., Gazieva G. A., Karnoukhova V. A., Kravchenko A. N. Diastereodivergent synthesis of dispiroheterocyclic structures comprising pyrrolidinyloxindole and imidazothiazolotriazine moieties // Organic and Biomolecular Chemistry. 2020. Vol. 18. No. 35. pp. 6905-6911.
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TY - JOUR
DO - 10.1039/D0OB01628D
UR - https://xlink.rsc.org/?DOI=D0OB01628D
TI - Diastereodivergent synthesis of dispiroheterocyclic structures comprising pyrrolidinyloxindole and imidazothiazolotriazine moieties
T2 - Organic and Biomolecular Chemistry
AU - Izmestev, Alexei N
AU - Gazieva, Galina A.
AU - Karnoukhova, Valentina A
AU - Kravchenko, Angelina N.
PY - 2020
DA - 2020/08/24
PB - Royal Society of Chemistry (RSC)
SP - 6905-6911
IS - 35
VL - 18
PMID - 32856678
SN - 1477-0520
SN - 1477-0539
ER -
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@article{2020_Izmestev,
author = {Alexei N Izmestev and Galina A. Gazieva and Valentina A Karnoukhova and Angelina N. Kravchenko},
title = {Diastereodivergent synthesis of dispiroheterocyclic structures comprising pyrrolidinyloxindole and imidazothiazolotriazine moieties},
journal = {Organic and Biomolecular Chemistry},
year = {2020},
volume = {18},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://xlink.rsc.org/?DOI=D0OB01628D},
number = {35},
pages = {6905--6911},
doi = {10.1039/D0OB01628D}
}
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MLA
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Izmestev, Alexei N., et al. “Diastereodivergent synthesis of dispiroheterocyclic structures comprising pyrrolidinyloxindole and imidazothiazolotriazine moieties.” Organic and Biomolecular Chemistry, vol. 18, no. 35, Aug. 2020, pp. 6905-6911. https://xlink.rsc.org/?DOI=D0OB01628D.
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