Chemical Society Reviews, volume 51, issue 5, pages 1640-1658
Copper-catalyzed radical relay in C(sp3)–H functionalization
Publication type: Journal Article
Publication date: 2022-02-10
Journal:
Chemical Society Reviews
Q1
Q1
SJR: 12.511
CiteScore: 80.8
Impact factor: 40.4
ISSN: 03060012, 14604744
General Chemistry
Abstract
Radical-involved transition metal (TM) catalysis has greatly enabled new reactivities in recent decades. Copper-catalyzed radical relay offers enormous potential in C(sp3)-H functionalization which combines the unique regioselectivity of hydrogen atom transfer (HAT) and the versatility of copper-catalyzed cross-coupling. More importantly, significant progress has been achieved in asymmetric C-H functionalization through judicious ligand design. This tutorial review will highlight the recent advances in this rapidly growing area, and we hope this survey will inspire future strategic developments for selective C(sp3)-H functionalization.
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Zhang Z., Chen P., Liu G. Copper-catalyzed radical relay in C(sp3)–H functionalization // Chemical Society Reviews. 2022. Vol. 51. No. 5. pp. 1640-1658.
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Zhang Z., Chen P., Liu G. Copper-catalyzed radical relay in C(sp3)–H functionalization // Chemical Society Reviews. 2022. Vol. 51. No. 5. pp. 1640-1658.
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TY - JOUR
DO - 10.1039/d1cs00727k
UR - https://doi.org/10.1039/d1cs00727k
TI - Copper-catalyzed radical relay in C(sp3)–H functionalization
T2 - Chemical Society Reviews
AU - Zhang, Zuxiao
AU - Chen, Pinhong
AU - Liu, Guosheng
PY - 2022
DA - 2022/02/10
PB - Royal Society of Chemistry (RSC)
SP - 1640-1658
IS - 5
VL - 51
SN - 0306-0012
SN - 1460-4744
ER -
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BibTex (up to 50 authors)
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@article{2022_Zhang,
author = {Zuxiao Zhang and Pinhong Chen and Guosheng Liu},
title = {Copper-catalyzed radical relay in C(sp3)–H functionalization},
journal = {Chemical Society Reviews},
year = {2022},
volume = {51},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039/d1cs00727k},
number = {5},
pages = {1640--1658},
doi = {10.1039/d1cs00727k}
}
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Zhang, Zuxiao, et al. “Copper-catalyzed radical relay in C(sp3)–H functionalization.” Chemical Society Reviews, vol. 51, no. 5, Feb. 2022, pp. 1640-1658. https://doi.org/10.1039/d1cs00727k.